Question
Using Sodium hydroxide solution, how would you distinguish: Ammonium sulphate from sodium sulphate.

Answer

Ammonium sulphate on reacting with sodium hydroxide liberates ammonia gas:
$
\left. NH _4\right)_2 SO _4( aq )+2 NaOH ( I ) \longrightarrow Na _2 SO _4( aq )+2 NH _3( I )+2 H _2 O ( I )
$
Sodium sulphate on reacting with sodium hydroxide undergoes the following change:
$
NaOH + Na _2 SO _4 \longrightarrow NaOH + Na _2 SO _4
$
However the products would be the same as the reactants, therefore providing no observation for a visible chemical reaction.

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