- A$N{a^ \oplus },{H^ \oplus }$
- B$N{a^ \oplus },{Cl^\Theta }$
- ✓${H^\Theta },C{l^\Theta }$
- D$O{H^\Theta },C{l^\Theta }$
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$(A)$ $\left[\mathrm{Pt}(\mathrm{en}) \mathrm{Cl}_2\right]$ $(B)$ $\left[\mathrm{Pt}(\mathrm{en})_2\right] \mathrm{Cl}_2$
$(C)$ $\left[\mathrm{Pt}(\text { en })_2 \mathrm{Cl}_2\right] \mathrm{Cl}_2$ $(D)$ $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]$
Statement $I$: Aqueous solution of $K _2 Cr _2 O$, is preferred as a primary standard in volumetric analysis over $Na _2 Cr _2 O$, aqueous solution
Statement $II:$ $K _2 Cr _2 O$, has a higher solubility in water than $Na _2 Cr _2 O _7$
In the light of the above statements, choose the correct answer from the options given below:
$C{H_3}CN\xrightarrow{{Na + {C_2}{H_5}OH}}X\xrightarrow{{HN{O_2}}}Y\mathop {\xrightarrow{{{K_2}C{r_2}{O_7}}}}\limits_{{H_2}S{O_4}} Z$

| Experiment No. | $\begin{array}{c}{[ A ]} \\ \left( mol dm ^{-3}\right)\end{array}$ | $\begin{array}{c}{[ B ]} \\ \left( mol dm ^{-3}\right)\end{array}$ | $\begin{array}{c}{[ C]} \\ \left( mol dm ^{-3}\right)\end{array}$ | Rate of reaction $\left( mol dm ^{-3} s ^{-1}\right)$ |
| $1$ | $0.2$ | $0.1$ | $0.1$ | $6.0 \times 10^{-5}$ |
| $2$ | $0.2$ | $0.2$ | $0.1$ | $6.0 \times 10^{-5}$ |
| $3$ | $0.2$ | $0.1$ | $0.2$ | $1.2 \times 10^{-4}$ |
| $4$ | $0.3$ | $0.1$ | $0.1$ | $9.0 \times 10^{-5}$ |
The rate of the reaction for $[ A ]=0.15 mol dm ^{-3},[ B ]=0.25 mol dm ^{-3}$ and $[ C ]=0.15 mol dm ^{-3}$ is found to be $Y \times 10^{-5} mol dm d ^{-3} s ^{-1}$. The value of $Y$ i. . . . . . .