MCQ
When $CrI_3$ oxidises to $Cr_2O_7^{-2}$ and $IO_4^-$ , equivalent mass of $CrI_3$ will be :-
  • A
    $\frac{M}{33}$
  • $\frac{M}{27}$
  • C
    $\frac{M}{28}$
  • D
    $\frac{M}{24}$

Answer

Correct option: B.
$\frac{M}{27}$
b
$\mathop {Cr{I_3}}\limits^{( + 3)( - 1)}  \to \mathop {C{r_2}O_7^{ - 2}}\limits^{ + 6}  + \mathop {IO_4^ - }\limits^{( + 7)} $

$n-$factor $\Rightarrow \mathrm{Cr}=(+3\, \mathrm{to}\,+6)=3 \mathrm{e}^{-} \,lo \mathrm{ss}$

$I=(-1 \text { to }+7) \times 3=24 \mathrm{e}^{-} \,lo \mathrm{ss}$

$n-$factor $=27$

$\therefore E=\frac{M}{27}$

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