Question
Which is most basic among the following?
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Answer
The basic character of a compound is determined by the stability of the conjugate acid.
Among the following alternatives, $D$ will be the most basic due to stabilization of the conjugate acid by the positive inductive as well as the hyperconjugation effect of the two methyl groups
Among the following alternatives, $D$ will be the most basic due to stabilization of the conjugate acid by the positive inductive as well as the hyperconjugation effect of the two methyl groups
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$\text{E}^\ominus_{\text{cr}_2\text{O}^{2-}_7/\text{cr}^{3+}}=1.33\text{V}\ \ \ \text{E}^\ominus_{\text{Cl}_2/\text{Cl}^-}=1.36\text{V}$
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→$\text{E}^\ominus_{\text{cr}_2\text{O}^{2-}_7/\text{cr}^{3+}}=1.33\text{V}\ \ \ \text{E}^\ominus_{\text{Cl}_2/\text{Cl}^-}=1.36\text{V}$
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