Question
Which of the following compounds has the highest boiling points?

Answer

The forces of attraction between the molecules of a compound get stronger as they get bigger in size and have more electrons. Also, for a straight-chain compound, the points of interaction between the molecules are more than for a branched compound having the same molecular formula. Thus $CH_3CH_2CH_2CH_2Cl$ has the highest melting point since it is the longest chain compound among the given options.

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