Question
Write following conversions:
- Nitrobenzene → acetanilide.
- Acetanilide → p-nitroaniline.
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Silver is electrodeposited on a metallic vessel of total surface area 500cm2 by passing a current of 0.5 amp for two hours. Calculate the thickness of silver deposited.
[Given: Density of silver = 10.5g cm-3, Atomic mass of silver = 108 amu, F = 96,500 C mol-1]
[Given: Density of silver = 10.5g cm-3, Atomic mass of silver = 108 amu, F = 96,500 C mol-1]
Write chemical reaction of aniline with benzoyl chloride and write the name of the product obtained.
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Ethyl amine is basic while acetamide is ampheteric. Explain the reason.
Give the structures of A, B and C in the following reaction:
$\text{C}_6\text{H}_5\text{NO}_2\xrightarrow[]{\text{Fe}/\text{HCl}}\text{A}\xrightarrow[273\text{K}]{\text{HNO}_2}\text{B}\xrightarrow[]{\text{C}_6\text{H}_5\text{OH}}\text{C}$
→$\text{C}_6\text{H}_5\text{NO}_2\xrightarrow[]{\text{Fe}/\text{HCl}}\text{A}\xrightarrow[273\text{K}]{\text{HNO}_2}\text{B}\xrightarrow[]{\text{C}_6\text{H}_5\text{OH}}\text{C}$
Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with II.
Column I | Column II | ||
(i) | CH3-o-CH3 | (a) |  |
(ii) |  | (b) | $\ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3 \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \text{CH}_3-\text{C}-\text{I}+\text{CH}_3\text{OH} \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$ |
(iii) | $\ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3 \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \text{H}_3\text{C}-\text{C}-\text{O}-\text{CH}_3 \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$ | (c) |  |
(iv) |  | (d) | CH3-OH + CH3-I |
(e) |  | ||
(f) |  | ||
(g) | $\ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3 \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \text{CH}_3-\text{C}-\text{OH}+\text{CH}_3\text{I} \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$ |
Define the following terms :
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