Question
Write IUPAC names of the following coordination compounds:
- $K_3[Fe(C_2O_4)_3]$
- $K_2[PdCl_4]$
✓
Answer
- Potassium trioxalatoferrate(III).
- Potassium tetrachloridopalladate(II).
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Neeta was experimenting in the lab to study the chemical reactivity of alcohols. She carried out a dehydration reaction of propanol at $140^\circ C$ to $180^\circ C.$ Different products were obtained at these two temperatures.
$a.$ Identify the major product formed at $140^\circ C$ and the substitution mechanism followed in this case.
$b.$ Identify the major product formed at $180^\circ C$ and the substitution mechanism followed in this case.
→$a.$ Identify the major product formed at $140^\circ C$ and the substitution mechanism followed in this case.
$b.$ Identify the major product formed at $180^\circ C$ and the substitution mechanism followed in this case.
How the following conversions can be carried out?
i. 2-Bromopropane to 1-bromopropane
ii. Chloroethane to butane
iii. Benzene to diphenyl
i. 2-Bromopropane to 1-bromopropane
ii. Chloroethane to butane
iii. Benzene to diphenyl
Explain the following terms giving a suitable example in each case:
- Ambident ligand.
- Denticity of a ligand.
- Crystal field splitting in an octahedral field.
Explain the nucleophilic substitution reaction of aldehydes and ketones with Grignard reagent (R'-Mg-X) with chemical equations ### Write only chemical reactions to obtain 1º, 2º and 3º alcohols from aldehyde andketone compounds.
Answer the following questions:
In the titration of $FeSO_4$ with $KMnO_4$ in the acidic medium, why is dil. $H_2SO_4$ used instead of dil. $HCl$?
→In the titration of $FeSO_4$ with $KMnO_4$ in the acidic medium, why is dil. $H_2SO_4$ used instead of dil. $HCl$?
What is stereochemistry ? Explain plane polarised light, optical activity and optical isomers.
The Fischer projection of D-Glucose is given alongside.
Give the Fischer projection of L-Glucose.
Give the Fischer projection of L-Glucose.
Discuss chemical properties of lanthanoids.
Write chemical reactions to show that open structure of D-glucose contains the following:
- Straight chain.
- Five alcohol groups.
- Aldehyde as carbonyl group.
The cell in which the following reaction occurs:
$2\text{Fe}^{3+}(\text{aq})+2\text{I}^-(\text{aq})\rightarrow2\text{Fe}^{2+}(\text{aq})+\text{I}_2(\text{s})\ \text{has}\ \text{E}^\circ_{\text{cell}}$ = 0.236 V at 298 K. Calculate the standard Gibbs energy and the equilibrium constant of the cell reaction.
→$2\text{Fe}^{3+}(\text{aq})+2\text{I}^-(\text{aq})\rightarrow2\text{Fe}^{2+}(\text{aq})+\text{I}_2(\text{s})\ \text{has}\ \text{E}^\circ_{\text{cell}}$ = 0.236 V at 298 K. Calculate the standard Gibbs energy and the equilibrium constant of the cell reaction.