- (a) 1215.4 A
Explanation:
From, $\text{V}=\frac{1}{\lambda}=\text{R}\Big(\frac{1}{\text{n}^2_1}-\frac{1}{\text{n}^2_2}\Big)$
n1 = 1, n2 = 2 for first spectral line of Lyman series,
$\frac{1}{\lambda}=1.097\times10^7\bigg(\frac{1}{1^2}-\frac{1}{1^2}\bigg)$
$=\frac{3\times1.097\times10^7}{4}\text{m}^{-1}$
$\lambda=\frac{4\times10^{-7}\text{m}}{3\times1.097}$
$=\frac{4000}{3\times1.0947}\text{A}=1215.4\text{A}$
- (d) 911.6 A
Explanation:
For wavelength limit, we put $\text{n}_2=\infty$
$\therefore\frac{1}{\lambda}=1.097\times10^7\Big(\frac{1}{1^2}-\frac{1}{\infty}\Big)$
$\lambda=\frac{1}{1.097\times10^7}$
$\text{m}=\frac{1000}{1.097}\text{A}=911.6\text{ A}$
- (b) 4.57 × 1014 Hz
Explanation:
For first line of Balmer series, n1 = 2, n2 = 3
$\text{V}=\frac{1}{\lambda}=\text{R}\Bigg(\frac{1}{\text{n}^2_1}-\frac{1}{\text{n}^2_2}\Bigg)$
$\text{V}=\frac{\text{c}}{\lambda}=\text{Rc}\Bigg(\frac{1}{\text{n}^2_1}-\frac{1}{\text{n}^2_2}\Bigg)$
= 1.097 × 107 × 3 × 108$\Bigg(\frac{1}{2_2}-\frac{1}{3_2}\Bigg)$
= 1.097 × 3 × 1015 × 3 $\frac{5}{36}$ 4.57 × 1014 Hz
- (d) n = 2 to n = 1
Explanation:
$\text{h}\upsilon_{2\rightarrow1}=-13.6\Bigg(\frac{1}{2_2}-\frac{1}{1_2}\Bigg)\text{eV}=10.2\text{eV}$
Emission is n = 2 → n = 1 i.e., higher n to lower n. Transition from lower to higher levels are absorption lines.
$13.6\Bigg(\frac{1}{6_2}-\frac{1}{2_2}\Bigg)=+13.6\times\frac{2}{9}$
This is < En = 2 → En = 1
- (a) 5 : 9
Explanation:
$\frac{1}{\lambda_\text{max}}=\text{R}\bigg[\frac{1}{2^2}-\frac{1}{3^2}\bigg]=\frac{5\text{R}}{36}$
$\frac{1}{\lambda_\text{max}}=\text{R}\bigg[\frac{1}{2^2}-\frac{1}{\infty}\bigg]=\frac{\text{R}}{4}$
$\Rightarrow\frac{\lambda_\text{max}}{\lambda_\text{max}}=\frac{5\text{R}}{36}\times\frac{4}{\text{R}}=\frac{5}{9}$