Question types

PART - 1 CH - 2 Structure of Atom question types

179 questions across 8 question groups — pick any mix to generate a Chemistry paper with step-by-step answer keys.

179
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8
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5
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Sample Questions

PART - 1 CH - 2 Structure of Atom questions

One sample from each question group in this chapter. Select any group above to see the full set with answer keys.

The value of orbital angular for d-electron will be:
  • A
    $\frac{4 h}{2 \pi}$
  • B
    $\frac{6 h}{2 \pi}$
  • C
    $\frac{\sqrt{12} h}{2 \pi}$
  • $\frac{\sqrt{6} h}{2 \pi}$

Answer: D.

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De-Broglie formula is:
  • A
    $\lambda=\frac{ h }{ mV }$
  • $\lambda=\frac{ h }{ mc }$
  • C
    $\lambda=\frac{ h }{ m \overline{ V }}$
  • D
    none of these

Answer: B.

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What does Bohr's atomic model explain?
  • A
    Hydrogen molecule
  • B
    Hydrogen spectrum
  • Spectrum of that atom or ion which has one electron
  • D
    $Li ^{+}$

Answer: C.

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The unpaired electrons in Al and Si are present in 3p orbital. Which electrons will experience more effective nuclear charge from the nucleus?
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Among the following pairs of orbitals which orbital will experience the larger effective nuclear charge? (i) 2s and 3s, (ii) 4d and 4f, (iii) 3d and 3p.
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The bromine atom possesses 35 electrons. It contains 6 electrons in $2 p$ orbital, 6 electrons in $3 p$ orbital and 5 electron in $4 p$ orbital. Which of these electron experiences the lowest effective nuclear charge?
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The quantum numbers of six electrons are given below. Arrange them in order of increasing energies. If any of these combination(s) has/have the same energy lists :
1.$n=4$$l=2$$m_l=-2$$m_s=-\frac{1}{2}$
2.$n=3$$l=2$$m_l=1$$m_s=+\frac{1}{2}$
3.$n=4$$l=1$$m_l=0$$m_s=+\frac{1}{2}$
4.$n=3$$l=2$$m_l=-2$$m_s=-\frac{1}{2}$
5.$n=3$$l=1$$m_l=-1$$m_s=+\frac{1}{2}$
6.$n=4$$l=1$$m_l=0$$m_s=+\frac{1}{2}$
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The velocity associated with a proton moving in a potential difference of 1000 V is $4.37 \times$ $10^5 ms^{-1}$. If the hockey ball of mass 0.1 kg is moving with this velocity. Calculate the wavelength associated with this velocity.
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(a) How many subshells are associated with $n =4$ ? (b) How many electrons will be present in the subshells having $m_s$ value of $-\frac{1}{2}$ for $n=4$ ?
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Similar to electron diffraction, neutron diffraction microscope is also used for the determination of the structure of molecules. If the wavelength used here is 800 pm , calculate the characteristic velocity associated with the neutron.
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Q 263 Marks Question3 Marks
A photon of wavelength $4 \times 10^{-7} m$ strikes on metal surface, the work function of the metal being 2.13 eV . Calculate (i) the energy of the photon (eV), (ii) the kinetic energy of the emission, and (iii) the velocity of the photoelectron ( $1 eV =1.6020 \times$ $\left.10^{-19} J\right)$.
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Q 283 Marks Question3 Marks
If the position of the electron is measured within an accuracy of $\pm 0.002 nm$, calculate the uncertainty in the momentum of the electron. Suppose the momentum of the electron is $\frac{h}{4 \pi_m \times 0.05 nm}$, is there any problem in defining this value.
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Q 293 Marks Question3 Marks
Calculate the wavelength for the emission transition if it starts from the orbit having radius 1.3225 nm and ends at 211.6 pm . Name the series to which this transition belongs and the region of the spectrum.
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Q 303 Marks Question3 Marks
The ejection of the photoelectron from the silver metal in the photoelectric effect experiment can be stopped by applying the voltage of 0.35 V when the radiation 256.7 nm is used. Calculate the work function for silver metal.
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Column AColumn B
(1) Zero energy of electron(a) 2s, 2p.
(2) Orbitals in second shell(b) 4
(3) Maximum number of electrons in dorbital(c) at infinite
(4) Number of lobes in d-orbital(d) 10
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Column AColumn B
(1) Shape of orbitals(a) $-13.6 \times \frac{ Z ^2}{n^2} eV$ per atom
(2) First postulate of Bohr model(b) Total values of 1
(3) Energy of electrons in Bohr's orbital $\left( E _{ n }\right)$(c) Azimuthal quantum numbers
(4) Number of subshells in any shell(d) $m V^2=\frac{ Ze ^2}{r}$
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Column AColumn B
(1) Energy mass equation of Einstein(a) $KE =\frac{1}{2} m v^2$
(2) Wavelength of Balmer series(b) Linear spectrum
(3) Atomic spectrum(c) $4000 Å-7000 Å$
(4) Kinetic energy(d) $E = mc ^2$
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Column AColumn B
(1) Nodal plane for $P _x$ orbital(a) 6s, 5p, 4d
(2) 3 unpaired electrons in nitrogen(b) yz
(3) Orbitals for n = 5, $l$=2 and m =0(c) Hund's law of maximum
(4) Orbitals for n+$l$ = 6(d) $5 dz ^2$
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Column AColumn B
(1) Wavenumber(a) Principal quantum numbers
(2) Radius of Bohr shell(b) $2 n^2$
(3) Maximum number of electrons in any orbital(c) $\frac{1}{\lambda}$
(4) K, L, M, N, O(d) $\frac{n^2}{Z} \times 0.529 Å$
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The work function for caesium atom is 1.9 eV . Calculate (a) the threshold wavelength and (b) the threshold frequency of the radiation. If the caesium element is irradiated with a wavelength 500 nm , calculate the kinetic energy and the velocity of the rejected photoelectron.
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(i) Calculate the total number of electrons present in one mole of methane.
(ii) Find (a) the total number and (b) the total mass of neutrons in 7 mg of 14C. (Assume that mass of a neutron $=1.675 \times 10^{-27} kg$ )
(iii) Find (a) the total number and (b) the total mass of protons in 34 mg of $NH _3$ at STP.
Will the answer change if the temperature and pressure are changed?
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