Question types

Electro Chemistry question types

57 questions across 6 question groups — pick any mix to generate a Chemistry paper with step-by-step answer keys.

57
Questions
6
Question groups
5
Question types
Sample Questions

Electro Chemistry questions

One sample from each question group in this chapter. Select any group above to see the full set with answer keys.

The electromotive force of the cell Zn | $ZnSO_{4}$ || $CuSO_{4}$ | Cu is 1.1 volt. Its cathode is:
  • A
    Zn
  • Cu
  • C
    $ZnSO_{4}$
  • D
    $CuSO_{4}$

Answer: B.

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Faraday's second law of electrolysis are related to:
  • A
    Atomic number of cation
  • B
    Atomic number of anion
  • Equivalent weight of electrolyte
  • D
    Speed of Cation

Answer: C.

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The standard reduction potential values of elements A, B and C are + 0.68 V, -2.50 V and -0.50 V respectively. The order of their reducing power is:
  • A
    $A > B > C$
  • B
    $A > C > B$
  • C
    $C > B > A$
  • $B > C > A$

Answer: D.

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How much charge is required for reduction of 1 mole of $Al^{3+}$ to Al?
  • $3.0 \times 10^{5} C$
  • B
    $28.95 \times 10^{5} C$
  • C
    $289.5 \times 10^{5} C$
  • D
    $2895 \times 10^{5} C$

Answer: A.

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The cell in which the following reaction occurs: $Fe_{(aq)}^{3+} + 2I_{(aq)}^{-} \longrightarrow 2Fe_{(aq)}^{2+} + I_{2(s)}$ has $E_{cell}^{0} = 0.236 V$ at 298 K. Calculate the standard Gibbs energy of the cell reaction. (Given: $1 F = 96500 C mol^{-1}$)
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(a) Calculate $\Delta G^{0}$ for the reaction
$Zn(s) + Cu^{2+}(aq) \longrightarrow Zn^{2+}(aq) + Cu(s)$.
Given: $E^{0}$ for $Zn^{2+}/Zn = -0.76 V$ and
$E^{0}$ for $Cu^{2+}/Cu = +0.34 V$,
$R = 8.314 J K^{-1} mol^{-1}$,
$F = 96500 C mol^{-1}$.
(b) Give two advantages of fuel cells.
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Calculate the mass of Ag deposited at cathode when a current of 2 amperes was passed through a solution of $AgNO_{3}$ for 15 minute. (Given: Molar mass of $Ag = 108 g mol^{-1}$, $1 F = 96500 C mol^{-1}$)
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Q 163 Marks Question3 Marks
$E_{\text {cell }}^0$ for the given redox reaction is 2.71 V
$Mg _{( s )}+ Cu _{(0.01 M )}^{2+} \longrightarrow \stackrel{2++ Cu _{( s )}}{ Mg _{(0.001 M )}^{2+}}$
Calculate $E_{\text {cell }}$ for the reaction. Write the direction of flow of current when an external opposite potential applied is
(i) less than 2.71 V and (ii) greater than 2.71 V .
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Q 173 Marks Question3 Marks
For the reaction $2AgCl_{(s)} + H_{2(g)}$ (1 atm) $\rightarrow$ $2Ag_{(s)} + 2H^{+} (0.1 M) + 2Cl^{-} (0.1M)$
$\Delta G^{0} = -43600 J$ at $25^{\circ}C$.
Calculate the emf of the cell. [$log 10^{-n} = -n$]
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Q 193 Marks Question3 Marks
Calculate $E _{ cell }^0$ for the following reaction at 298 K.
$2 Cr _{(s)}+3 Fe ^{2+}\left(0.1 M \rightarrow 2 Cr ^{3+}(0.01 M )+3 Fe _{(s)}\right.$
Given : $E _{\left( Cr ^{3+} / Cr \right)}^{\circ}=-0.74 V, E _{\left( Fe ^{2+} / Fe \right)}^{\circ}=-0.44 V$
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A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes $FeSO_{4}$ and $ZnSO_{4}$ until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y. (Molar mass: $Fe = 56 g mol^{-1}, Zn = 65.3 g mol^{-1}, 1 F = 96500 C mol^{-1}$)
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How much electricity in terms of Faraday is required to produce:
(i) 20.0 g of Ca from molten $CaCl_{2}$, (ii) 40.0 g of Al from molten $Al_{2}O_{3}$.
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(a) Out of the following pairs, predict with reason which pair will allow greater conduction electricity:
(i) Silver wire at $30^{\circ}C$ or silver wire at $60^{\circ}C.$
(ii) 0.1 M $CH_{3}COOH$ solution or 1 M $CH_{3}COOH$ solution.
(iii) KCl solution at $20^{\circ}C$ or KCl solution at $50^{\circ}C$.
(b) Give two points of differences between electrochemical and electrolytic cells.
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Write the cell reaction and calculate the emf of the following cell at 298 K
$S n _{( s )}\left| S n ^{2+}( 0 . 0 0 4 ~ M ) \| H ^{+}( 0 . 0 2 0 ~ M )\right| H _2( g ) \overline{( 1 )} \mid P t s$ (Given : $ES _{ n }{ }^{2+} / Sn =- 0 . 1 4 V$ )
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