Question 13 Marks
Show that the radius of the orbit in hydrogen atom varies as $n^2,$ where n is the principal quantum number of the atom.
Answer
View full question & answer→According to the Bohr's theory of hydrogen atom, the angular momentum of revolving electron is given by
$\text{m v r} =\frac{n h}{2 \pi} ....(i)$
where, m = mass of the electron $, v =$ velocity of the electron.
$r =$ radius of the orbit $, h =$ Planck's constant and $n = $ principal quantum number of the atom."
If an electron of mass m and velocity v is moving in a circular orbit of radius r, then the centripetal force is given by
$F _{ C }= mv ^2 / r ...(ii)$
Also, if the charge on the nucleus is Ze, then the force of electrostatic attraction between the nucleus and the electron will provide the necessary centripetal force
$\Rightarrow F _{ C }= F _{ e }$
$\Rightarrow \frac{m v^2}{r}=\frac{k e^2}{r^2} \quad[\therefore Z=1]$
$\Rightarrow r=\frac{e^2 \cdot k}{m v^2} ....(iii)$
$r=\frac{k e^2 4 \pi^2 m^2 r^2}{m \cdot n^2 h^2} \ [$from eq. $(i)]$
$\Rightarrow r=\frac{n^2 h^2}{k e^2 4 \pi^2 m} \Rightarrow r \propto n^2$
$\text{m v r} =\frac{n h}{2 \pi} ....(i)$
where, m = mass of the electron $, v =$ velocity of the electron.
$r =$ radius of the orbit $, h =$ Planck's constant and $n = $ principal quantum number of the atom."
If an electron of mass m and velocity v is moving in a circular orbit of radius r, then the centripetal force is given by
$F _{ C }= mv ^2 / r ...(ii)$
Also, if the charge on the nucleus is Ze, then the force of electrostatic attraction between the nucleus and the electron will provide the necessary centripetal force
$\Rightarrow F _{ C }= F _{ e }$
$\Rightarrow \frac{m v^2}{r}=\frac{k e^2}{r^2} \quad[\therefore Z=1]$
$\Rightarrow r=\frac{e^2 \cdot k}{m v^2} ....(iii)$
$r=\frac{k e^2 4 \pi^2 m^2 r^2}{m \cdot n^2 h^2} \ [$from eq. $(i)]$
$\Rightarrow r=\frac{n^2 h^2}{k e^2 4 \pi^2 m} \Rightarrow r \propto n^2$



