Question 13 Marks
A sample of paramagnetic salt contains $2.0 \times 10^{24}$ atomic dipoles each of dipole moment $1.5 \times 10^{-23} \mathrm{~J} \mathrm{~T}^{-1}$. The sample is placed under a homogeneous magnetic field of 0.64 T , and cooled to a temperature of 4.2 K . The degree of magnetic saturation achieved is equal to $15 \%$. What is the total dipole moment of the sample for a magnetic field of 0.98 T and a temperature of 2.8 K ? (Assume Curie's law)
Answer
View full question & answer→Number of atomic dipoles, $\mathrm{n}=2.0 \times 10^{24}$
Dipole moment of each atomic dipole, $\mathrm{M}=1.5 \times 10^{-23} \mathrm{~J} \mathrm{~T}^{-1}$
When the magnetic field, $\mathrm{B}_1=0.64 \mathrm{~T}$
The sample is cooled to a temperature, $T_1=4.2^{\circ} \mathrm{K}$
Total dipole moment of the atomic dipole, $\mathrm{M}_{\text {tot }}=\mathrm{n} \times \mathrm{M}$
$ =2 \times 10^{24} \times 1.5 \times 10^{-23} $
$=30 \mathrm{JT}^{-1}$
Magnetic saturation is achieved at 15%.
Hence, effective dipole moment, $\text{M}_1=\frac{15}{100}\times30=4.5\text{ J T}^{-1}$
When the magnetic field, $B_2= 0.98\ T$
Temperature, $T_2= 2.8°\ K$
Its total dipole moment $= M_2$
According to Curie’s law, we have the ratio of two magnetic dipoles as:
$\frac{\text{M}_2}{\text{M}_1}=\frac{\text{B}_2}{\text{B}_1}\times\frac{\text{T}_1}{\text{T}_2}$
$\therefore\ \text{M}_2=\frac{\text{B}_2\text{T}_1\text{M}_1}{\text{B}_1\text{T}_2}$
$=\frac{0.98\times4.2\times4.5}{2.8\times0.64}=10.336\text{ J T}^{-1}$
Therefore, $10.336\text{ J T}^{-1}$ is the total dipole moment of the sample for a magnetic field of 0.98 T and a temperature of 2.8 K.
Dipole moment of each atomic dipole, $\mathrm{M}=1.5 \times 10^{-23} \mathrm{~J} \mathrm{~T}^{-1}$
When the magnetic field, $\mathrm{B}_1=0.64 \mathrm{~T}$
The sample is cooled to a temperature, $T_1=4.2^{\circ} \mathrm{K}$
Total dipole moment of the atomic dipole, $\mathrm{M}_{\text {tot }}=\mathrm{n} \times \mathrm{M}$
$ =2 \times 10^{24} \times 1.5 \times 10^{-23} $
$=30 \mathrm{JT}^{-1}$
Magnetic saturation is achieved at 15%.
Hence, effective dipole moment, $\text{M}_1=\frac{15}{100}\times30=4.5\text{ J T}^{-1}$
When the magnetic field, $B_2= 0.98\ T$
Temperature, $T_2= 2.8°\ K$
Its total dipole moment $= M_2$
According to Curie’s law, we have the ratio of two magnetic dipoles as:
$\frac{\text{M}_2}{\text{M}_1}=\frac{\text{B}_2}{\text{B}_1}\times\frac{\text{T}_1}{\text{T}_2}$
$\therefore\ \text{M}_2=\frac{\text{B}_2\text{T}_1\text{M}_1}{\text{B}_1\text{T}_2}$
$=\frac{0.98\times4.2\times4.5}{2.8\times0.64}=10.336\text{ J T}^{-1}$
Therefore, $10.336\text{ J T}^{-1}$ is the total dipole moment of the sample for a magnetic field of 0.98 T and a temperature of 2.8 K.







