\(\underset{{{2}^{o}}\,carbonium\,ion}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}} \\
\,\,\,\,\,\,\,\,\,\,\,\,\,| \\
C{{H}_{3}}\overset{+}{\mathop{-C}}\,H-C-C{{H}_{3}} \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\, \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}} \\
\end{matrix}}}\,\) \(+O{{H}^{-}}\xrightarrow[\operatorname{Re}arrangement]{Methyl\,shift}\)
\(\underset{2,3-dimethyl-2-Butene\,[Most\,synnetrial\,structure]}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,C{{H}_{3}}\,\,C{{H}_{3}} \\
|\,\,\,\,\,\,\,\,\,| \\
C{{H}_{3}}-C=C-C{{H}_{3}} \\
\end{matrix}}}\,\) \(\xleftarrow[-{{H}^{+}}]{}\) \(\underset{{{3}^{o}}\,Carbonium\,ion\,(More\,stable)}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,C{{H}_{3}} \\
\,\,|\,\,\,\,\,\,\,\,\,\,\,\,| \\
C{{H}_{3}}-CH-\underset{+}{\mathop{C}}\,-C{{H}_{3}} \\
\end{matrix}}}\,\)
$n - Bu -\equiv\frac{(i) n-BuLi,n - C _{5} H _{11} Cl}{(ii) Lindlar\,\, cat, H _{2}}$