d
$PV = nRT [ n \rightarrow$ Np.of moles $]$
$\log ( PV )=\log ( nRT )$
$\log P +\log V =\log n+\log R t$
Differentiate it
$\frac{\Delta P }{ P }+\frac{\Delta V }{ V }=\frac{\Delta n }{ n }+\frac{\Delta T }{ T }$
$\because$ It is filled in a rigid cylinder
$\Delta P =0$
$\frac{\Delta V }{ V } \times 100=-10$
$\frac{\Delta T }{ T } \times 100=20$
$\therefore-10=\frac{\Delta n }{ n } \times 100+20$
$\frac{\Delta n }{ n } \times 100=-30$
$\because n =\frac{ m }{ M }$
Where $m \rightarrow$ Mass of gas leaked
$M \rightarrow$ Molar mass
$\therefore \frac{\Delta m }{ m } \times 100=-30$
$\therefore 30 \%$ gas will leak out