$2AB_{2(g)} \rightleftharpoons 2AB_{(g)} + B_{2(g)}$
વિયોજન અંશ $x$ એ $1$ ની સાપેક્ષમાં નાનો છે, તો વિયોજન અંશ $x$ ની સંતુલન અયળાંક $K_p$ અને કુલ દબાણ $P$ સાથેના સંબંધની રજૂઆત ..........
$\text { Initial moles } \;\; 1 \quad \;\;\;\;\quad 0 \quad \quad \quad \quad 0$
At equil. $\quad 2(1-x)\quad \quad 2 x\quad \quad \quad x$
where, $x=$ degree of dissociation
Total moles at equilibrium
$=2-2 x+2 x+x=(2+x)$
$\text { So, } p_{A B 2}= \frac{2(1-x) p}{(2+x)}, p_{A B}=\frac{2 x p}{(2+x)}$
$p_{B 2}= \frac{x p}{(2+x)}$
$K_{p}=\frac{p_{A} s}{\left(p_{A}\right)^{2}\left(P_{B 2}\right)}$
$=\frac{\left(\frac{2 r p}{2+p}\right)^{2}\left[\left(\frac{x}{2+x}\right) p\right]}{\left[\left(\frac{2 a-x}{(2+x)}\right) p\right]}$
$=\frac{x^{3} p}{(2+x)(1-x)^{2}}$
$=\frac{x^{3} p}{2}[\cdots x < < < 1 \text { and } 2]$
$x =\left(\frac{2 K p}{p}\right)^{1 / 3}$
So, $(1-x) \approx ; 1(2+x) \approx 2$
$2S{O_2} + {O_2}$ $\rightleftharpoons$ $2S{O_3} + Q$ $Cal$
(આપેલ: $\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$ )