$(i)\,\,\Delta H_f^o\,\,of\,{H_2}{O_{(\ell )}}\, = \,\, - 68.3\,K\,\,cal\,\,mo{l^{ - 1}}$
$(ii)\,\,\Delta H_{comb}^o\,\,of\,{C_2}{H_2}\, = \,\, - 337.2\,K\,\,cal\,\,mo{l^{ - 1}}$
$(iii)\,\,\Delta H_{comb}^o\,\,of\,\,{C_2}{H_4}\,\, = \,\, - \,363.7\,\,K\,\,cal\,\,mo{l^{ - 1}} $
$(a)\,\,q + w$ $ (b)\,\,q$
$(c)\,\,w$ $ (d)\,\,H -TS$