$P _{12} V _2^\gamma= P _{34} V_3^\gamma \quad \dots(i)$
$P _{34} V_4^\gamma= P _{12} V_1^\gamma \quad \dots(ii)$
Multiply $(i)$ and $(ii)$
$V _2^\gamma \cdot V _4^\gamma= V _1^\gamma \cdot V _3^\gamma$
$V _2 V _4= V _1 V _3 \Rightarrow\left(\frac{ V _2}{ V _3}=\frac{ V _1}{ V _4}\right)= K _4$
$\eta=\frac{\text { Work done }}{ Q _{\text {suppl. }}}=1-\frac{ Q _{\text {rej }}}{ Q _{\text {supp }}}=1-\frac{ n _{ C / P } \Delta T _{34}}{ n _{ C / P } \Delta T _{12}}$
$=1-\frac{\Delta( PV )_{34}}{\Delta( PV )_{12}}=1-\frac{ P _{34}\left( V _3- V _4\right)}{ P _{12}\left( V _2- V _1\right)}$

| $List-I$ | $List-II$ |
| ($I$) $10^{-3} kg$ of water at $100^{\circ} C$ is converted to steam at the same temperature, at a pressure of $10^5 Pa$. The volume of the system changes from $10^{-6} m ^3$ to $10^{-3} m ^3$ in the process. Latent heat of water $=2250 kJ / kg$. | ($P$) $2 kJ$ |
| ($II$) $0.2$ moles of a rigid diatomic ideal gas with volume $V$ at temperature $500 K$ undergoes an isobaric expansion to volume $3 V$. Assume $R=8.0 Jmol ^1 K^{-1}$. | ($Q$) $7 kJ$ |
| ($III$) On mole of a monatomic ideal gas is compressed adiabatically from volume $V=\frac{1}{3} m^3$ and pressure $2 kPa$ to volume $\frac{v}{8}$ | ($R$) $4 kJ$ |
| ($IV$) Three moles of a diatomic ideal gas whose molecules can vibrate, is given $9 kJ$ of heat and undergoes isobaric expansion. | ($S$) $5 kJ$ |
| ($T$) $3 kJ$ |
Which one of the following options is correct?