\({\text{P}}\) કુલ \({\text{ = }}\left( {{p_A}^0 \times \frac{1}{2}} \right) + \left( {{p_B}^0 \times \frac{1}{2}} \right)\) \((\because \,\,1:1\) મોલ)
\(\therefore 400 = \frac{{{P_A}^0}}{2} + \frac{{{P_B}^0}}{2}\)
\(\therefore \,\,\,\,{p_A}^0 + {p_B}^0 = 800\) ........... \((1)\)
\({\text{P}}\) કુલ \({\text{ = }}{{\text{p}}_{\text{A}}}^{\text{0}}{{\text{X}}_{\text{A}}}{\text{ + }}{{\text{p}}_{\text{B}}}^{\text{0}}{{\text{X}}_{\text{B}}}\,\,\,\)
\(\,\therefore \,\,\,350 = \left( {{p_A}^0 \times \frac{1}{3}} \right) + \left( {{p_B}^0 \times \frac{2}{3}} \right)\) (\(\because \,\,1:2\) મોલ)
\(\therefore 350 = \frac{{{p_A}^0}}{3} + \frac{{2{p_B}^0}}{3}\,\)
\(\,\therefore \,\,\,\,{p_A}^0 + 2{p_B}^0 = 1050\) ........... \((2)\)
પરિણામ \((1)\) અને \((2)\) પરથી,\({\text{P}}{{\text{A}}^{\text{0}}}{\text{ = 550}}\) મિમી, \({{\text{p}}_{\text{B}}}^{\text{0}}{\text{ = 250}}\) મિમી
(નજીકનાં પૂર્ણાંકમાં રાઉન્ડ ઑફ) $\left[ K _{ b }=0.52 \,K \,kg \,mol ^{-1}\right]$