Question
Compare the structures of $\text{H}_2\text{O}$ and $\text{H}_2\text{O}_2$.

Answer

In water, O is $\text{sp}^3$ hybridized. Due to stronger lone pair-lone pair repulsions than bond pair-bond pair repulsions, the HOH bond angle decreases from 109.5° to 104.5°. Thus water molecule has a bent structure.

$\text{H}_2\text{O}_2$ has a non-planar structure. The O—H bonds are in different planes. Thus, the structure of $\text{H}_2\text{O}_2$ is like an open book.

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