Question
Distinguish between a sigma and a pi bond.

Answer

 

Sr. No.

Pi bond

Sigma bond

1

Pi bond is formed by lateral overlapping of orbitals.

Sigma bond is formed by end to end overlapping of orbitals.

2

It is comparatively weak bond.

It is comparatively strong bond.

3

There is only one overlapping orbital is p-p.

The overlapping orbitals are s-s, s-p, p-p.

4

Rotation around pi- bond is restricted.

Rotation is possible around sigma bond.

5

Electron cloud is not symmetrical about the line joining 2 nuclei.

Electron cloud is symmetrical about the line joining 2 nuclei.

6

It is having 2 electron clouds one above the plane of atomic nuclei and one below the plane of atomic nuclei.

It is having 1 electron cloud and that is symmetrical about the inter-nuclear axis.

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