Explain the following: (i) Markownikov's Law (ii) Peroxide effect - Vidyadip

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Explain the following: (i) Markownikov's Law (ii) Peroxide effect

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When heated in air, the alkali metals form various oxides. Mention the oxides formed by $Li, Na$ and $K$.

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The reactant which is entirely consumed in reaction is known as limiting reagent. In the reaction 2A + 4B → 3C + 4D, when 5 moles of A react with 6 moles of B, then

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Draw shape of the following molecules on the basis of VSEPR theory:

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For the reaction:

$\text{N}_2(\text{g})+3\text{H}_2(\text{g})\rightleftharpoons2\text{NH}_3(\text{g}),$
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Colculate the value of $K_c$ for the reaction at the same temperature R = 0.083L bar $K^{-1}mol^{-1}$.

What is the effect of increasing pressure in the reactions? Give reason.

$\text{PCl}_5(\text{g})\rightleftharpoons\text{PCl}_3(\text{g})+\text{Cl}_2\text{(g)}$
$\text{N}_2(\text{g})+\text{O}_2(\text{g})\rightleftharpoons2\text{NO(g)}$

Complete the equations for:

$\text{BF}_3+\text{LiH}\rightarrow$
$\text{B}_2\text{H}_6+\text{H}_2\text{O}\rightarrow$

Give reasons:

Conc $HNO_3$ is transported in aluminium container.
Graphite is used as lubricant.
Lead (IV) chloride is highly unstable towards heat.

Explain why cation are smaller and anions larger in radii than their parent atoms?

Arrange the following according to given property

$\text{CH}_3\stackrel{\oplus \ \ \ }{\text{CH}}_2,\text{C}_6\text{H}_5-\stackrel{\oplus\ \ \ \ }{\text{CH}}_2,(\text{CH}_3)_3\stackrel{\oplus \ \ \ \ }{\text{CH}},$
$\text{CH}_2=\text{CH}-\stackrel{\oplus\ \ \ \ }{\text{CH}}_2$ (decreasing order of stability)

$\text{HC}\equiv\text{C}^{\ominus},\text{Ch}_2=\stackrel{\ominus\ \ \ \ \ \ }{\text{CH}_2},\text{CH}_3-\stackrel{\ominus\ \ \ \ \ }{\text{CH}_2},\stackrel{\ominus \ \ \ \ \ }{\text{CH}_3}$ (increasing order of stabillity)
$\text{C}_6\text{H}_5\stackrel{\bf. \ \ \ \ }{\text{CHCH}_3},\text{C}_6\text{H}_5\text{CH}_2\stackrel{\bf.\ \ \ \ \ }{\text{CH}_2},\text{C}_6\text{H}_5\stackrel{\bf.}{\text{C}}_3(\text{CH}_3)_2$ (increasing order of stabillity)
$\text{CH}_3-\stackrel{\oplus \ \ \ \ }{\text{CH}}-\text{O}-\text{CH}_3,\text{CH}_3-\stackrel{\oplus \ \ \ \ }{\text{CH}},-\text{OCH}_3,$

${\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{O}}\\{\ \ \ \ \ \ \ \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \\ \|}\\\ \text{CH}_3-\stackrel{\oplus \ \ \ \ }{\text{CH}}\text{C}-\text{OCH}_3$ (decreasing order of stability)