| તત્વ | $M^{3+}/ M$ | $M^+/M$ |
| $Al$ | $-1.66$ | $+0.55$ |
| $Tl$ | $+1.26$ | $-0.34$ |
આ માહિતીને આધારે ક્યુ વિધાન સાચું છે?
$(ii)\mathop {T{l^{3 + }}}\limits_{Less\,\,stable} \,\xrightarrow{{{E^o}\, = \, - + 1.26}}Tl\,\xleftarrow{{{E^o}\, = \, - 0.34}}\mathop {T{l^ + }}\limits_{Most\,\,\,stable} $
$Tl^+$ has negative electrode potential $(E^o = - 0.34)$ means, it does not prefer to convert into $Tl$ but reverse must be preferred that's why it is more stable than $Tl^{3+}$ $(E^o\,=\,+\,1.26)$ In $Al$, $Al^{3+}$ is more stable $E^o=\,-\,1.66$ than $Al^+$ $(E^o\,=\,+0.55)$ and also from $Tl^+$ due to more negative value of $E^o$. Therefore, by comparison it confirms that $Tl^+$ is more stable than $Al^+$.
$(i)$ $Zn| Zn^{2+} {(1\,M)}|| Cu^{2+}{(0.1\,M)}| Cu$
$(ii)$ $Zn| Zn^{2+} {(1\,M)}|| Cu^{2+}(1\,M) |Cu $
$(iii)$ $Zn| Zn^{2+} {(0.1\,M)}|| Cu^{2+}{(1\,M)}| Cu$