\({G}=\frac{1}{{R}}=\frac{1}{0.243}\, \Omega^{-1}\)
\({k}={G} \times {G}^{*}\)
\({G}^{*}=\frac{{k}}{{G}}=\frac{1.07 \times 10^{6}}{\frac{1}{0.243}} \simeq 26 \times 10^{4}\, {~m}^{-1}\)
$F{e^{ + 2 }} + 2{e^ - }\, \to \,Fe\,;\,\,\,\,{E^o} = - 0.440\,V$
$F{e^{ + 3 }} + 3{e^ - }\, \to \,Fe\,;\,\,\,\,{E^o} = - 0.036\,V$
તો $F{e^{ + 3 }} + {e^ - } \to \,F{e^{ + 2 }}$ માટે પ્રમાણિત ઇલેક્ટ્રોન પોટેન્શિયલ $({E^o})$ .............. $\mathrm{V}$ છે.
$(F = 96500 \,C\, mol^{-1})$
આપેલ $: \frac{2.303 RT }{ F }=0.06 V$
$Pd _{( aq )}^{2+}+2 e ^{-} \rightleftharpoons Pd ( s ) \quad E ^{\circ}=0.83\,V$
$PdCl _4^{2-}( aq )+2 e ^{-} \rightleftharpoons Pd ( s )+4 Cl ^{-}( aq )$
$E ^{\circ}=0.65\,V$