\(\mathrm{Co}^{3+}(\text { strong field ligand }) \Rightarrow 3 \mathrm{~d}^6\left(\mathrm{t}_{2 \mathrm{~g}}^6, \mathrm{e}_{\mathrm{g}}^0\right),\)
Hybridisation : \(d^2 \mathrm{sp}^3\)
Inner obital complex(spin paired complex)
Pairing will take place.
\(\left[\mathrm{CoF}_6\right]^{3-}\)
\(\mathrm{Co}^{3+}\) (weak field ligand) \(\Rightarrow 3 \mathrm{~d}^6\left(\mathrm{t}_{2 \mathrm{~g}}^4, \mathrm{e}_{\mathrm{g}}^2\right)\)
Hybridisation : \(\mathrm{sp}^3 \mathrm{~d}^2\)
Outer orbital complex (spin free complex) no pairing will take place
${\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},}$
${\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}}$
ઉદીપક | પ્રક્રિયા |
$(A)$ $TiCl_4$ | $(i)$ Wacker process |
$(B)$ $PdCl_2$ | $(ii)$ Ziegler - Natta polymerization |
$(C)$ $CuCl_2$ | $(iii)$ Contact process |
$(D)$ $V_2O_5$ | $(iv)$ Deacon's process |
Column $-I\,-$ Column $-II\,-$ Column $\,-III$