According to Drago's rule lone pair on phosphorus resides in almost pure s-orbital, hence due to non-directionalnature, its overlapping tendency is greatly reduced in comparison to a lone pair present in hybrid orbital, which is directional as present in \(\overset{\,\,\centerdot \,\,\centerdot \,\,\,\,\,\,\,\,}{\mathop{\text{N}{{\text{H}}_{3}}}}\,\).
$(I)$ $XeF_6 +NaF \to Na^+ [XeF_7]^-$ $(II)$ $2PCl_5(s) \to [PCl_4]^+[PCl_6]^-$
$(III)$ $[Al(H_2O)_6]^{3+} + H_2O \to [Al(H_2O)_5OH]^{2+} + H_3O^+$
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