$I.\,SeO_3^{2 - } + BrO_3^ - + {H^ + } \to SeO_4^{2 - } + B{r_2} + {H_2}O$
$II.\,BrO_3^ - + AsO_2^ - + {H_2}O \to B{r^ - } + AsO_4^{3 - } + {H^ + }$
$(II)\,\mathop {BrO_3^{- }}\limits^{ + 5} + \mathop {AsO_2^ - }\limits^{ + 3} + {H_2}O \to \mathop {B{r^ - }}\limits^{ - 1} + \mathop {AsO_4^{3 - }}\limits^{ + 5} + {H^ + }$
In reaction $(II)$
gm. eq. of $BrO_3^-=$ gm. eq. of $AsO_2^-$
$n_{BrO_3^-} \times 6=n_{AsO_2^-} \times 2$
$ = \frac{{12.5}}{{1000}} \times \frac{1}{{25}} \times 2 = {10^{ - 3}}$
${n_{BrO_3^ - }} = \frac{{{{10}^{ - 3}}}}{6}$
In reaction $(I)$
moles of $BrO_3^-$ consumed
$ = \frac{{70}}{{1000}} \times \frac{1}{{60}} - \frac{{{{10}^{ - 3}}}}{6} = {10^{ - 3}}$
gm eq. of $SeO_3^{2-} = gm. eq. of BrO_3^-$
$n_{SeO_3^{2-}} \times 2 = 10^{-3} \times 5$ ;
$n_{SeO_3^{2-}} = 2.5 \times 10^{-3}$
[મોલર દળ ${KCl}=74.5$ ]