નીચેની પ્રકિયા માં
$(i) \,\,\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - C - CH - C{H_3}} \\
{\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,OH}
\end{array}\,\xrightarrow{{{H^ + }/heat}}\,\,\mathop A\limits_{[Major\,product]} \, + \,\mathop B\limits_{[Minor\,product]} $
$(ii)\,\, A\xrightarrow[{in\,\,absence\,\,\,of\,peroxide}]{{HBr,\,dark}}\,\,\mathop C\limits_{[Major\,product]} \, + \,\mathop D\limits_{[Minor\,product]} $
મુખ્ય નીપજ $(A)$ અને $(C)$ અનુક્રમે શું હશે ?
AIPMT 2011, Diffcult
Download our app for free and get started
b
$\begin{matrix}
\begin{matrix}
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix} \\
C{{H}_{3}}CH-CHC{{H}_{3}} \\
\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\, \\
\,\,\,\,\,\,\,\,\,\,\,\, \,\,\,OH \\
\end{matrix}$ $\xrightarrow[{heat}]{{{H^ + }}}$ $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - CH - \mathop C\limits_ \oplus H - C{H_3}}
\end{array}$ $\xrightarrow{{1\,,\,2\, - \,hydride\,shift}}$ $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - \mathop C\limits_ \oplus - C{H_2} - C{H_3}}
\end{array}$ $\xrightarrow{{ - \,{H^ + }}}$ $\underset{\begin{smallmatrix}
(A) \\
Major
\end{smallmatrix}}{\mathop{\begin{matrix}
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-C=CH-C{{H}_{3}} \\
\end{matrix}}}\,$ $+$ $\underset{\begin{smallmatrix}
(B) \\
Minor
\end{smallmatrix}}{\mathop{\begin{matrix}
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-CH-CH=C{{H}_{2}} \\
\end{matrix}}}\,$
$\begin{matrix}
\begin{matrix}
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix} \\
C{{H}_{3}}CH-CHC{{H}_{3}} \\
\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\, \\
\,\,\,\,\,\,\,\,\,\,\,\, \,\,\,OH \\
\end{matrix}$ $\xrightarrow[{heat}]{{{H^ + }}}$ $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - CH - \mathop C\limits_ \oplus H - C{H_3}}
\end{array}$ $\xrightarrow{{1\,,\,2\, - \,hydride\,shift}}$ $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - \mathop C\limits_ \oplus - C{H_2} - C{H_3}}
\end{array}$ $\xrightarrow{{ - \,{H^ + }}}$ $\underset{\begin{smallmatrix}
(A) \\
Major
\end{smallmatrix}}{\mathop{\begin{matrix}
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-C=CH-C{{H}_{3}} \\
\end{matrix}}}\,$ $+$ $\underset{\begin{smallmatrix}
(B) \\
Minor
\end{smallmatrix}}{\mathop{\begin{matrix}
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-CH-CH=C{{H}_{2}} \\
\end{matrix}}}\,$
$\underset{\begin{smallmatrix}
(A) \\
Major
\end{smallmatrix}}{\mathop{\begin{matrix}
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-C=CH-C{{H}_{3}} \\
\end{matrix}}}\,$ $\xrightarrow[{in\,\,absence\,\,of\,\,peroxide}]{{HBr\,,\,dark}}$ $\mathop {\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,}
\end{array}\,\,\,\,\,\,\,\,} \\
{C{H_3} - C - C{H_2} - C{H_3}} \\
{\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{\,Br\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}}\limits_{(C)\,\,\,major} $ $\mathop {\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - CH - CH - C{H_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,Br\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}}\limits_{(D)\,\,\,minor} $
Download our appand get started for free
Experience the future of education. Simply download our apps or reach out to us for more information. Let's shape the future of learning together!No signup needed.*
Similar Questions
- 1પ્રોપિનમાંથી પ્રોપેન $-1-$ ઓલ નીચેના પૈકી કોના દ્વારા બનાવી શકાય ?View Solution
- 2View Solutionફિનોલનું સલ્ફોનેશન નીચેનામાંથી કઇ નિપજ આવશે ?
- 3View Solutionફિનોલિક સમૂહ માટેની લાક્ષણિક સમૂહ કસોટી કઇ છે ?
- 4View Solutionનીચે આપેલ પ્રક્રિયામાં સૌથી વધુ સ્થિર નીપજ શોધો.
- 5નીચેની પ્રકિયા ના ક્રમ માં પ્રકિયક $X$ અને નીપજ $Y$ શું હશે ?View Solution
- 6View Solutionપ્રુફ સ્પીરીટ (કદથી) એ નીચેનામાંથી ક્યુ મિશ્રણ છે ?
- 7ઉપરોક્ત પ્રકિયા નો પ્રકીયક $A$ શું હશે ?View Solution
- 8View Solutionનીચેનામાંથી ક્યા સંયોજનનું ઓકિસડેશન કરવાથી મિથાઇલ ઇથાઇલ કિટોન મળશે ?
- 9કોને $HIO_4$ દ્વારા છૂટા કરવામાં આવ્યા નથી ?View Solution
$I :$ ગ્લિસરોલ $II : $ ગ્લાયકોલ
$III : 1 , 3-$ પ્રોપિનડાયોલ $IV :$ મિથોકસી $ -2- $ પ્રોપેનોલ
- 10નીચેની પ્રકિયા ની મુખ્ય નીપજ કઈ હશે ?View Solution
$\begin{array}{*{20}{c}}
{OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - CH - C{H_2} - C{H_2} - OH}
\end{array}\,$ ${\xrightarrow[{Pyridine{\kern 1pt} cold}]{{Cr{O_3}}}}$ નીપજ