Question
Read the passage given below and answer the following questions from (i) to (vi).
The atomic theory of matter was first proposed on afirm scientific basis by JohnDalton, a British schoolteacher in 1808. His theory, called Dalton’s atomictheory, regarded the atom as the ultimate particle ofmatter Dalton’s atomic theory was able to explainthe law of conservation of mass, law of constantcomposition and law of multiple proportion verysuccessfully. However, it failed to explain the results ofmany experiments.In mid 1850s many scientists mainlyFaraday began to study electrical dischargein partially evacuated tubes, known ascathode ray discharge tubes.Electrical discharge carried out in the modifiedcathode ray tube led to the discovery of canalrays carrying positively charged particles. Thecharacteristics of these positively chargedparticles are listed below.
  1. Unlike cathode rays, mass of positivelycharged particles depends upon thenature of gas present in the cathode raytube. These are simply the positivelycharged gaseous ions.
  2. The charge to mass ratio of the particlesdepends on the gas from which theseoriginate.
  3. Some of the positively charged particlescarry a multiple of the fundamental unitof electrical charge.
  4. The behaviour of these particles in themagnetic or electrical field is opposite tothat observed for electron or cathoderays.
The smallest and lightest positive ion wasobtained from hydrogen and was called
proton. This positively charged particle wascharacterised in 1919. Later, a need was feltfor the presence of electrically neutral particleas one of the constituent of atom. Theseparticles were discovered by Chadwick (1932)by bombarding a thin sheet of beryllium byα-particles. When electrically neutral particleshaving a mass slightly greater than that ofprotons were emitted. He named theseparticles as neutrons.J. J. Thomson, in 1898, proposed that an atom possesses a spherical shape (radiusapproximately 10–10 m) in which the positivecharge is uniformly distributed. The electronsare embedded into it in such a manner as togive the most stable electrostatic arrangementMany different names are given tothis model, for example, plum pudding, raisinpudding or watermelon. This model can be visualised as a pudding or watermelon ofpositive charge with plums or seeds (electrons)embedded into it. An important feature of thismodel is that the mass of the atom is assumed to be uniformly distributed over theatom.Rutherford and his students (Hans Geiger andErnest Marsden) bombarded very thin gold foilwith α–particles. Rutherford’s famous α–particle scattering experiment.The observations of Scattering experiment are as follows-:
  1. most of the α–particles passed throughthe gold foil undeflected.
  2. a small fraction of the α–particles wasdeflected by small angles.
  3. a very few α–particles (∼1 in 20,000)bounced back, that is, were deflected bynearly 180°.
On the basis of observations andconclusions from this experiment, Rutherford proposed the nuclearmodel of atom. According to this model:
  1. The positive charge and most of the massof the atom was densely concentrated inextremely small region. This very smallportion of the atom was called nucleusby Rutherford.
  2. The nucleus is surrounded by electronsthat move around the nucleus with a veryhigh speed in circular paths called orbits.Thus, Rutherford’s model of atomresembles the solar system in which thenucleus plays the role of sun and theelectrons that of revolving planets.
  3. Electrons and the nucleus are held together by electrostatic forces of attraction.
  1. The atomic theory of matter was first proposed on afirm scientific basis by:
  1. John Dalton
  2. Ernest Rutherford
  3. J.Thomson
  4. Henry Moseley
  1. The cathode rays start from … and move towards the….
  1. Anode, Cathode
  2. Centre, Anode
  3. Cathod, Anode
  4. Cathod, Centre
  1. Negativelycharged particles in atoms, called…
  1. Protons
  2. Electrons
  3. Neutron
  4. Positron
  1. The smallest and lightest positive ion wasobtained from …. and was called proton.
  1. Oxygen
  2. Nitrogen
  3. Carbon
  4. Hydrogen
  1. Electrically neutral particles having a mass slightly greater than that of protons, these particles termed as:
  1. Protons
  2. Electrons
  3. Neutron
  4. Positron
  1. J.J. Thomson’s atomic model is also named as:
  1. Plum pudding
  2. Raisin pudding
  3. Watermelon
  4. All the above

Answer

  1. (a) John Dalton
  1. (c) Cathod, Anode
  1. (b) Electrons
  1. (d) Hydrogen
  1. (c) Neutron
  1. (d) All the above

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Read the passage given below and answer the following questions from (i) to (v).
A system in thermodynamics refers to that part of universe in which observations are made and remaining universe constitutes the surroundings. The surroundings include everything other than the system. System and the surroundings together constitute the universe. The universe = The system + The surroundings However, the entire universe other than the system is not affected by the changes taking place in the system. Therefore, for all practical purposes, the surroundings are that portion of the remaining universe which can interact with the system. Usually, the region of space in the neighbourhood of the system constitutes its surroundings.
The wall that separates the system from the surroundings is called boundary.
Types of the System We, further classify the systems according to the movements of matter and energy in or out of the system.
  1. Open System In an open system, there is exchange of energy and matter between system and surroundings. The presence of reactants in an open beaker is an example of an open system. Here the boundary is an imaginary surface enclosing the beaker and reactants.
  2. Closed System In a closed system, there is no exchange of matter, but exchange of energy is possible between system and the surroundings. The presence of reactants in a closed vessel made of conducting material e.g., copper or steel is an example of a closed system.
  3. Isolated System In an isolated system, there is no exchange of energy or matter between the system and the surroundings. The presence of reactants in a thermos flask or any other closed insulated vessel is an example of an isolated system.
The State of the System The system must be described in order to make any useful calculations by specifying quantitatively each of the properties such as its pressure (p), volume (V), and temperature (T) as well as the composition of the system. We need to describe the system by specifying it before and after the change. You would recall from your Physics course that the state of a system in mechanics is completely specified at a given instant of time, by the position and velocity of each mass point of the system. In thermodynamics, a different and much simpler concept of the state of a system is introduced. It does not need detailed knowledge of motion of each particle because, we deal with average measurable properties of the system. We specify the state of the system by state functions or state variables. The state of a thermodynamic system is described by its measurable or macroscopic (bulk) properties. We can describe the state of a gas by quoting its pressure (p), volume (V), temperature (T), amount (n) etc. Variables like p, V, T are called state variables or state functions because their values depend only on the state of the system and not on how it is reached. In order to completely define the state of a system it is not necessary to define all the properties of the system; as only a certain number of properties can be varied independently. This number depends on the nature of the system. Once these minimum number of macroscopic properties are fixed, others automatically have definite values. The state of the surroundings can never be completely specified; fortunately it is not necessary to do so.
By conventions of IUPAC in chemical thermodynamics. The q is positive, when heat is transferred from the surroundings to the system and the internal energy of the system increases and q is negative when heat is transferred from system to the surroundings resulting in decrease of the internal energy of the system.
Let us consider the general case in which a change of state is brought about both by doing work and by transfer of heat. We write change in internal energy for this case as: $ \triangle{\text{U}}=\text{q}+\text{w}$
For a given change in state, q and w can vary depending on how the change is carried out. However, $\text{q}+\text{w}=\triangle{\text{U}}$ will depend only on initial and final state. It will be independent of the way the change is carried out. If there is no transfer of energy as heat or as work (isolated system) i.e., if w = 0 and q = 0, then $ \triangle{\text{U}}=0.$ The equation i.e., $ \triangle{\text{U}}=\text{q}+\text{w}$ is mathematical statement of the first law of thermodynamics, which states that The energy of an isolated system is constant. It is commonly stated as the law of conservation of energy i.e., energy can neither be created nor be destroyed.
  1. $\triangle\text{U}=\ ....$
  1. q + w
  2. q + v
  3. q + m
  4. q + z
  1. Which of the following is not an example of state variable?
  1. Pressure
  2. Ionic radius
  3. Volume
  4. Amount
  1. $\triangle\text{U}=\text{q}+\text{w}$ is termed as …
  1. Third law of thermodynamics
  2. Second law of thermodynamics
  3. First law of thermodynamics
  4. None of above
  1. A … in thermodynamics refers to that part of universe in which observations are made.
  1. Universe
  2. System
  3. Surrounding
  4. Boundary
  1. Which of the following is a type if system ?
  1. Open system
  2. Closed system
  3. Lsolated system
  4. All the above
IUPAC (International Union of Pure and Applied Chemistry) system of nomenclature. Common names are useful and in many cases indispensable, particularly when the alternative systematic names are lengthy and complicated. A systematic name of an organic compound is generally derived by identifying the parent hydrocarbon and the functional group(s) attached to it. By using prefixes and suffixes, the parent name can be modified to obtain the actual name. In a branched-chain compound, small chains of carbon atoms are attached at one or more carbon atoms of the parent chain. The small carbon chains (branches) are called alkyl groups. An alkyl group is derived from a saturated hydrocarbon by removing a hydrogen atom from carbon. Abbreviations are used for some alkyl groups. For example, methyl is abbreviated as Me, ethyl as Et, propyl as Pr and butyl as Bu.

1. Draw the structure of 3-Ethyl-4,4-dimethylheptane. (1)
2. How is the numbering in branched chain hydrocarbon done?
3. Derive the structure of 2-Chlorohexane. (2)
OR
Why $CH _4$ after becoming- $CH _3$ called a methyl group? (2)
When anions and cations approach each other, the valence shell of anions are pulled towards the cation nucleus and thus, the shape of the anion is deformed. The phenomenon of deformation of anion by a cation is known as polarization and the ability of the cation to polarize the anion is called as polarizing power of cation. Due to polarization, sharing of electrons occurs between two ions to some extent and the bond shows some covalent character.
The magnitude of polarization depends upon a number of factors.

1. Out of $AlCl _3$ and $AlI _3$ which halides show maximum polarization? (1)
2. Out of $AlCl _3$ and $CaCl _2$ which one is more covalent in nature? (1)
3. The non-aqueous solvent like ether is added to the mixture of $LiCl , NaCl$ and KCl . Which will be extracted into the ether? (2)
OR
Out of $CaF _2$ and $CaI _2$ which one has a minimum melting point? (2)
The existing large number of organic compounds and their ever-increasing numbers has made it necessary to classify them on the basis of their structures. Organic compounds are broadly classified as open-chain compounds which are also called aliphatic compounds. Aliphatic compounds further classified as homocyclic and heterocyclic compounds. Aromatic compounds are special types of compounds. Alicyclic compounds, aromatic compounds may also have heteroatom in the ring. Such compounds are called heterocyclic aromatic compounds. Organic compounds can also be classified on the basis of functional groups, into families or homologous series. The members of a homologous series can be represented by general molecular formula and the successive members differ from each other in a molecular formula by a $- CH _2$ unit.

1. The successive members of a homologous series differ by which mass of amu? (1)
2. Does Pyridine, pyrrole, thiophene are all heteroaromatic compounds (1)
3. Difference between heterocyclic and homocyclic compound. (2)
OR
Is tetrahydrofuran is aromatic compounds? (2)
The ionic character of metallic halides tends toward covalent nature as per Fajan's rule. Such covalent halides behave as non-metal in their higher oxidation states. The property to hydrolyse to give oxy-acids of the element and corresponding hydro halogen acid for most non-metallic elements proceeds exceptionally in the way, keeping oxidation number of element and halide sam in oxo-acids.
Non-polar halides are immiscible in water, as they do not show hydrolysis, but halides of some elements with empty d-orbital undergo hydrolysis. Stability of halides of the higher state is governed by the inert-pair effect.

1. How does halide undergo hydrolysis to give oxy-acids of underlined element $PCl _3$ ? (1)
2. Out of $NCl _3$ and $BCl _3$ undergoes hydrolysis to form oxy-acids? Write the chemical reaction for the correct answer. (1)
3. Out of $PbCl _4, PbF _4, PbI _4$ and $PbBr _4$ which one doesn't exist? (2)
OR
Non-Polar halides are immiscible in water. Why? (2)
Read the passage given below and answer the following questions from 1 to 5 .
In p-block elements the last electron enters the outermost p orbital. As we know that the number of p orbitals is three and, therefore, the maximum number of electrons that can be accommodated in a set of p orbitals is six. Consequently there are six groups of p-block elements in the periodic table numbering from 13 to 18 . Boron, carbon, nitrogen, oxygen, fluorine and helium head the groups. Their valence shell electronic configuration is $ns ^2 np ^{1-}$ ${ }^6$ (except for He). The inner core of the electronic configuration may, however, differ. The difference in inner core of elements greatly influences their physical properties (such as atomic and ionic radii, ionisation enthalpy, etc.) as well as chemical properties. The occurrence of oxidation states two unit less than the group oxidation states are sometime attributed to the 'inert pair effect'.
Group 13 elements: the boron family This group elements show a wide variation in properties. Boron is a typical non-metal, aluminium is a metal but shows many chemical similarities to boron, and gallium, indium, thallium and nihonium are almost exclusively metallic in character. Boron is a fairly rare element, mainly occurs as orthoboric acid, $\left( H _3 BO _3\right)$, borax, $Na _2 B_4 O _7 \cdot 10 H _2 O$, and kernite, $Na _2 B_4 O _7 \cdot 4 H _2 O$. In India borax occurs in Puga Valley (Ladakh) and Sambhar Lake (Rajasthan). The abundance of boron in earth crust is less than $0.0001 \%$ by mass. There are two isotopic forms of boron $10 B(19 \%)$ and $11 B(81 \%)$. Aluminium is the most abundant metal and the third most abundant element in the earth's crust ( $8.3 \%$ by mass) after oxygen ( $45.5 \%$ ) and $Si (27.7 \%)$. Bauxite, $Al 2 O 3.2 H _2 O$ and cryolite, Na3AIF6 are the important minerals of aluminium. In India it is found as mica in Madhya Pradesh, Karnataka, Orissa and Jammu. Gallium, indium and thallium are less abundant elements in nature. Nihonium has symbol Nh, atomic number 113 , atomic mass $286 g mol ^{-1}$ and electronic configuration $[R n] 5 f^{14} 6 d^{10} 7 s^2 7 p ^2$. So far it has been prepared in small amount and half life of its most stable isotope is 20 seconds. Due to these reasons its chemistry has not been established. Nihonium is a synthetically prepared radioactive element. Here atomic, physical and chemical properties of elements of this group leaving nihonium are discussed below.
The outer electronic configuration of these elements is $n s 2 n{ }^1$. A close look at the electronic configuration suggests that while boron and aluminium have noble gas core, gallium and indium have noble gas plus 10 d electrons, and thallium has noble gas plus 14 f - electrons plus 10 d -electron cores. Thus, the electronic structures of these elements are more complex than for the first two groups of elements discussed in unit 10. This difference in electronic structures affects the other properties and consequently the chemistry of all the elements of this group. Atomic Radii On moving down the group, for each successive member one extra shell of electrons is added and, therefore, atomic radius is expected to increase. However, a deviation can be seen. Atomic radius of Ga is less than that of Al. This can be understood from the variation in the inner core of the electronic configuration. The presence of additional 10 d -electrons offer only poor screening effect (Unit 2) for the outer electrons from the increased nuclear charge in gallium. Consequently, the atomic radius of gallium ( 135 pm ) is less than that of aluminium (143 pm ).
Boron is non-metallic in nature. It is extremely hard and black coloured solid. It exists in many allotropic forms. Due to very strong crystalline lattice, boron has unusually high melting point. Rest of the members are soft metals with low melting point and high electrical conductivity. It is worthwhile to note that gallium with unusually low melting point ( 303 K ), could exist in liquid state during summer. Its high boiling point ( 2676 K ) makes it a useful material for measuring high temperatures. Density of the elements increases down the group from boron to thallium.
  1. There are … groups of p–block elements in the periodic table.
  1. six
  2. seven
  3. eight
  4. two
  1. Boron is … in nature.
  1. metallic
  2. non-metallic
  3. metalloid
  4. All the above
  1. Boiling point of gallium is …
  1. 303K
  2. 1345K
  3. 2676 K
  4. 1854K
  1. The occurrence of oxidation states two unit less than the group oxidation states are sometime attributed to the …
  1. loan pair effect
  2. middle pair effect
  3. outer pair effect
  4. inert pair effect
  1. Density of the elements … down the group from boron to thallium.
  1. increases
  2. decreases
  3. remains constant
  4. none of above
Read the passage given below and answer the following questions from 1 to 5.
Oxidation state and trends in chemical Reactivity Due to small size of boron, the sum of its first Three ionization enthalpies is very high. This Prevents it to form +3 ions and forces it to form Only covalent compounds. But as we move from B to Al, the sum of the first three ionisation Enthalpies of Al considerably decreases, and Is therefore able to form $Al^{3+}$ ions. In fact, Aluminium is a highly electropositive metal. However, down the group, due to poor Shielding effect of intervening d and f orbitals, The increased effective nuclear charge holds ns Electrons tightly (responsible for inert pair Effect) and thereby, restricting their Participation in bonding. As a result of this, Only p-orbital electron may be involved in Bonding. In fact in Ga, In and Tl, both +1 and +3 oxidation states are observed. The relative Stability of +1 oxidation state progressively Increases for heavier elements: A l< Ga < In< Tl. In Thallium +1 oxidation state is predominant whereas the +3 oxidation state is highly Oxidising in character. The compounds in +1 oxidation state, as expected from energy Considerations, are more ionic than those in +3 oxidation state.
Important trends and anomalous properties of boron – certain important trends can be observed in the chemical behaviour of group 13 elements. The tri-chlorides, bromides and iodides of all these elements being covalent in nature are hydrolysed in water. Species like tetrahedral $[M(OH)_4]^–$ and octahedral $[M(H_2O)6]^{3+}$, except in boron, exist in aqueous medium. The monomeric trihalides, being electron deficient, are strong Lewis acids. Boron trifluoride easily reacts with Lewis bases such as $NH_3$ to complete octet around boron. It is due to the absence of d orbitals that the maximum covalence of B is 4. Since the d orbitals are available with Al and other elements, the maximum covalence can be expected beyond 4. Most of the other metal halides (e.g., $AlCl_3$) are dimerised through halogen bridging (e.g., $Al2Cl_6$). The metal species completes its octet by accepting electrons from halogen in these halogen bridged molecules.
i) Reactivity towards air Boron is unreactive in crystalline form. Aluminium forms a very thin oxide layer on The surface which protects the metal from Further attack. Amorphous boron and Aluminium metal on heating in air form $B_2O_3$ And $Al_2O_3$ respectively. With dinitrogen at high Temperature they form nitrides. The nature of these oxides varies down the Group. Boron trioxide is acidic and reacts with Basic (metallic) oxides forming metal borates. Aluminium and gallium oxides are amphoteric And those of indium and thallium are basic in Their properties.
ii) Reactivity towards acids and alkalies Boron does not react with acids and alkalies Even at moderate temperature; but aluminium Dissolves in mineral acids and aqueous alkalies And thus shows amphoteric character. Aluminium dissolves in dilute HCl and Liberates dihydrogen.
$2Al(s) + 6HCl (aq) \rightarrow 2Al_3^+ (aq) + 6Cl^– (aq) + 3H_2 (g)$
However, concentrated nitric acid renders Aluminium passive by forming a protective Oxide layer on the surface. Aluminium also reacts with aqueous alkali And liberates dihydrogen.
$2Al (s) + 2NaOH(aq) + 6H_2O(l) \rightarrow 2 Na+ [Al(OH)_4]^– (aq) + 3H_2(g)$
Sodium Tetrahydroxoaluminate(III).
iii) Reactivity towards halogens These elements react with halogens to form Trihalides (except TlI3). $2E(s) + 3 X_2 (g) \rightarrow 2EX_3 (s) (X = F, Cl, Br, I)$
Borax- It is the most important compound of boron. It is a white crystalline solid of formula $Na_2B_4O_7⋅10H_2O$. In fact it contains the Tetranuclear units and correct Formula; therefore, is $Na2 [B4O5 (OH) 4].8H2O$. Borax dissolves in water to give an alkaline Solution.
$Na_2B_4O7 + 7H_2O \rightarrow 2NaOH + 4H_3BO_3$
On heating, borax first loses water Molecules and swells up. On further heating it Turns into a transparent liquid, which solidifies Into glass like material known as borax Bead. $Na_2B_4O_7.10H_2O \rightarrow Na^2B_4O_7\rightarrow 2NaBO_2+ B2O_3​​​​​​​$
Metaborate Boric Anhydride The metaborates of many transition metals Have characteristic colours and, therefore, Borax bead test can be used to identify them In the laboratory. For example, when borax is Heated in a Bunsen burner flame with CoO on A loop of platinum wire, a blue coloured Co(BO2) 2 bead is formed.
Orthoboric acid, $H_3BO_3$ is a white crystalline Solid, with soapy touch. It is sparingly soluble In water but highly soluble in hot water. It can Be prepared by acidifying an aqueous solution Of borax.
$Na_2B_4O_7 + 2HCl + 5H_2O \rightarrow 2NaCl + 4B(OH)_3​​​​​​​$
It is also formed by the hydrolysis (reaction With water or dilute acid) of most boron Compounds (halides, hydrides, etc.). It has a layer structure in which planar $BO_3$ units are Joined by hydrogen.
  1. Boron is … in crystalline form.
  1. unreactive
  2. highly reactive
  3. less reactive
  4. only (a) or (c)
  1. Orthoboric acid is …
  1. Amorphous
  2. Crystalline
  3. Polyamorphous
  4. None of above
  1. Aluminium and gallium oxides are … in their properties.
  1. acidic
  2. Basic
  3. amphoteric
  4. None of above
  1. Indium and thallium are … in their properties.
  1. acidic
  2. Alkali
  3. amphoteric
  4. basic
  1. Aluminium is a highly … metal.
  1. electronegative
  2. Neutral
  3. electropositive
  4. None of above
Read the passage given below and answer the following questions from 1 to 5.
Hydrogen has the simplest atomic structure among all the elements around us in Nature. In atomic form it consists of only one proton and one electron. However, in elemental form it exists as a diatomic $(H_2)$ molecule and is called dihydrogen. It forms more compounds than any other element. Do you know that the global concern related to energy can be overcome to a great extent by the use of hydrogen as a source of energy? In fact, hydrogen is of great industrial importance as you will learn in this unit. Hydrogen is the first element in the periodic table. However, its placement in the periodic table has been a subject of discussion in the past. As you know by now that the elements in the periodic table are arranged according to their electronic configurations. Hydrogen has electronic configuration $1s^1$. On one hand, its electronic configuration is similar to the outer electronic configuration $(ns^1)$ of alkali metals , which belong to the first group of the periodic table. On the other hand, like halogens (with $ns^2 np^5$ configuration belonging to the seventeenth group of the periodic table), it is short by one electron to the corresponding noble gas configuration, helium $(1s^2)$. Hydrogen, therefore, has resemblance to alkali metals, which lose one electron to form unipositive ions, as well as with halogens, which gain one electron to form uninegative ion. Like alkali metals, hydrogen forms oxides, halides and sulphides. However, unlike alkali metals, it has a very high ionization enthalpy and does not possess metallic characteristics under normal conditions. In fact, in terms of ionization enthalpy, hydrogen resembles more with halogens, $\triangle _iH$ of Li is $520\ kJ\ mol^{–1}$, F is $1680\ kJ\ mol^{–1}$and that of H is $1312\ kJ\ mol^{–1}$. Like halogens, it forms a diatomic molecule, combines with elements to form hydrides and a large number of covalent compounds. However, in terms of reactivity, it is very low as compared to halogens.
Inspite of the fact that hydrogen, to a certain extent resembles both with alkali metals and halogens, it differs from them as well. Now the pertinent question arises as where should it be placed in the periodic table? Loss of the electron from hydrogen atom results in nucleus $(H^+) of ~1.5 \times 10^{–3}\ pm$ size. This is extremely small as compared to normal atomic and ionic sizes of 50 to 200pm. As a consequence, $H^+$ does not exist freely and is always associated with other atoms or molecules. Thus, it is unique in behaviour and is, therefore, best placed separately in the periodic table. Occurrence – Dihydrogen $H^2$ is the most abundant element in the universe $(70 \%$ of the total mass of the universe) and is the principal element in the solar atmosphere. The giant planets Jupiter and Saturn consist mostly of hydrogen. However, due to its light nature, it is much less abundant (0.15% by mass) in the earth’s atmosphere. Of course, in the combined form it constitutes $15.4 \%$ of the earth’s crust and the oceans. In the combined form besides in water, it occurs in plant and animal tissues, carbohydrates, proteins, hydrides including hydrocarbons and many other compounds.
Hydrogen has three isotopes: protium, 1H, deuterium, 2H or D and tritium, 3H or T. These isotopes differ from one another in respect of the presence of neutrons. Ordinary hydrogen, protium, has no neutrons, deuterium (also known as heavy hydrogen) has one and tritium has two neutrons in the nucleus. In the year 1934, an American scientist, Harold C. Urey, got Nobel Prize for separating hydrogen isotope of mass number 2 by physical methods. The predominant form is protium. Terrestrial hydrogen contains 0.0156% of deuterium mostly in the form of HD. The tritium concentration is about one atom per 1018 atoms of protium. Of these isotopes, only tritium is radioactive and emits low energy $\beta\text{ -particles}(\text{t}\frac{1}{2}12.33\text{ years})$
  1. Hydrogen has electronic configuration ..
  1. $1s^1$
  2. $1s^2$
  3. $2s^1$
  4. $2s^2$
  1. Ionisation enthalpy of hydrogen is ..
  1. $520\ kJ\ mol^{–1}$​​​​​​​
  2. $1312\ kJ\ mol^{–1}$
  3. $1249\ kJ\ mol^{–1}$
  4. $950\ kJ\ mol^{–1}$
  1. Hydrogen has … Isotopes.
  1. 1
  2. 2
  3. 3
  4. 4
  1. got Nobel Prize for separating hydrogen isotope of mass number 2 by physical methods.
  1. Nyholm
  2. Gillespie
  3. Heitler
  4. Harold C. Urey
  1. tritium is radioactive and emits low energy…. particles.
  1. $\alpha$
  2. $\beta$
  3. $\gamma$
  4. $\sigma$
Read the passage given below and answer the following questions from $1$ to $5$.
It is prepared by complete combustion of Carbon and carbon containing fuels in excess Of air.
$\text{C(s)}+\text{O}_2\text{(g)}\xrightarrow{\triangle}\text{CO}_2\text{(g)}$
$\text{CH}_4\text{(g)}+2\text{O}_2\text{(g)}\rightarrow\text{CO}_2\text{(g)}+2\text{H}_2\text{O}\text{(g)}$
In the laboratory it is conveniently Prepared by the action of dilute HCl on calcium Carbonate.
$CaCO_3 (s) + 2HCl (aq) \rightarrow CaCl_2 (aq) + CO_2(g) + H_2O(l)$
$\text{H}_2\text{CO}_3(\text{aq})+\text{H}_2\text{O}\text{(l)}\rightleftharpoons\text{HCO}_3^-\text{(aq)}+\text{H}_3\text{O}^+\text{(aq)}$
$\text{H}\text{CO}_3^-(\text{aq})+\text{H}_2\text{O}\text{(l)}\rightleftharpoons\text{CO}_3^{2-}\text{(aq)}+\text{H}_3\text{O}^+\text{(aq)}$
Buffer system helps to Maintain pH of blood between $7.26$ to $7.42$. Being acidic in nature, it combines with alkalies To form metal carbonates. Carbon dioxide, which is normally present To the extent of $\sim0.03 %$ by volume in the Atmosphere, is removed from it by the process Known as photosynthesis. It is the process By which green plants convert atmospheric $CO_2$ into carbohydrates such as glucose. The Overall chemical change can be expressed as:
$6\text{CO}_2+12\text{H}_2\text{O}\xrightarrow[\text{Chlorophyll}]{\text{hv}}\text{C}_6\text{H}_{12}\text{O}_6+6\text{O}_2$
By this process plants make food for Themselves as well as for animals and human Beings. Unlike $CO$, it is not poisonous. But the Increase in combustion of fossil fuels and Decomposition of limestone for cement Manufacture in recent years seem to increase The $CO_2$ content of the atmosphere. This may Lead to increase in green house effect and Thus, raise the temperature of the atmosphere Which might have serious consequences. Carbon dioxide can be obtained as a solid In the form of dry ice by allowing the liquified $CO_2$ to expand rapidly. Dry ice is used as a Refrigerant for ice-cream and frozen food. Gaseous $CO_2$ is extensively used to carbonate Soft drinks. Being heavy and non-supporter Of combustion it is used as fire extinguisher. A Substantial amount of $CO_2$ is used to Manufacture urea. In $CO_2$ molecule carbon atom undergoes Sp hybridisation. Two sp hybridised orbitals Of carbon atom overlap with two p orbitals of Oxygen atoms to make two sigma bonds while Other two electrons of carbon atom are involved.

In $\text{p}\pi-\text{p}\pi$ bonding with oxyglargeen atom. This Results in its linear shape $[$with both $C–O$ bonds Of equal length $(115 pm)]$ with no dipole Moment. The resonance structures are shown Below: Resonance structures of carbon dioxide.
Silicon Dioxide, $SiO_2 95 \%$ of the earth’s crust is made up of silica And silicates. Silicon dioxide, commonly known As silica, occurs in several crystallographic Forms. Quartz, cristobalite and tridymite are Some of the crystalline forms of silica, and they Are interconvertable at suitable temperature. Silicon dioxide is a covalent, three-dimensional network solid in which each silicon atom is Covalently bonded in a tetrahedral manner to Four oxygen atoms. Each oxygen atom in turn Covalently bonded to another silicon atoms as Shown in diagram. Each corner is Shared with another tetrahedron. The entire Crystal may be considered as giant molecule In which eight membered rings are formed with Alternate silicon and oxygen atoms. Silica in its normal form is almost non- Reactive because of very high $Si—O$ bond Enthalpy. It resists the attack by halogens, Dihydrogen and most of the acids and metals Even at elevated temperatures. However, it is Attacked by HF and NaOH.
$SiO_2 + 2NaOH \rightarrow Na2SiO_3 + H_2O SiO_2 + 4HF \rightarrow SiF_4 + 2H_2O$
Quartz is extensively used as a piezoelectric Material; it has made possible to develop extremely Accurate clocks, modern radio and television Broadcasting and mobile radio communications. Silica gel is used as a drying agent and as a support For chromatographic materials and catalysts. Kieselghur, an amorphous form of silica is used In filtration plants.
Silicones are a group of organosilicon polymers, Which have $(R_2SiO)$ as a repeating unit. The Starting materials for the manufacture of Silicones are alkyl or aryl substituted silicon Chlorides, RnSiCl(4–n), where R is alkyl or aryl Group. When methyl chloride reacts with Silicon in the presence of copper as a catalyst At a temperature $573K$ various types of methyl substituted chlorosilane of formula $MeSiCl_3, Me_2SiCl_2, Me3SiCl$ with small amount of $Me4Si$ Are formed. Hydrolysis of dimethyl- Dichlorosilane, $(CH_3) 2SiCl_2$ followed by Condensation polymerisation yields straight Chain polymers.
A large number of silicates minerals exist in Nature. Some of the examples are feldspar, Zeolites, mica and asbestos. The basic structural unit of silicates is $SiO_4^{4–}$ In which silicon atom is bonded to four Oxygen atoms in tetrahedron fashion. In Silicates either the discrete unit is present or A number of such units are joined together Via corners by sharing $1, 2, 3$ or $4$ oxygen Atoms per silicate units. When silicate units Are linked together, they form chain, ring, Sheet or three-dimensional structures. Negative charge on silicate structure is Neutralised by positively charged metal ions. If all the four corners are shared with other Tetrahedral units, three-dimensional network Is formed. Two important man-made silicates are Glass and cement. Zeolites If aluminium atoms replace few silicon atoms In three-dimensional network of silicon dioxide, Overall structure known as aluminosilicate, Acquires a negative charge. Cations such as $Na+, K+$ Or $Ca_2+$ balance the negative charge. Examples are feldspar and zeolites.
Zeolites are Widely used as a catalyst in petrochemical Industries for cracking of hydrocarbons and Isomerisation, e.g., $ZSM-5$ (A type of zeolite) Used to convert alcohols directly into gasoline. Hydrated zeolites are used as ion exchangers In softening of “hard” water.
  1. … is used as a Refrigerant for ice-cream and frozen food.
  1. Dry ice
  2. Wet ice
  3. Crescent Ice
  4. Nugget Ice
  1. $H_2CO_3$ is a …
  1. strong dibasic acid
  2. weak dibasic acid
  3. weak diacidic base
  4. Strong diacidic base
  1. … is extensively used as a piezoelectric Material.
  1. Glass
  2. Ferrite
  3. Quartz
  4. Saphire
  1. … an amorphous form of silica is used In filtration plants.
  1. Ferrite
  2. Quartz
  3. Saphire
  4. Kieselghur
  1. Which of the following is not an example of silicate mineral ?
  1. feldspar
  2. mica
  3. asbestos
  4. hematite
There are many observable patterns in thephysical and chemical properties of elementsas we descend in a group or move across aperiod in the Periodic Table.Atomic Radius the determination of the atomic sizecannot be precise. In other words, there is no practical way by which the size of an individualatom can be measured. However, an estimateof the atomic size can be made by knowing thedistance between the atoms in the combinedstate. One practical approach to estimate thesize of an atom of a non-metallic element is tomeasure the distance between two atoms whenthey are bound together by a single bond in acovalent molecule and from this value, the“Covalent Radius” For metals, we define theterm “Metallic Radius” which is taken as halfthe internuclear distance separating the metalcores in the metallic crystal. Atomic Radius to refer to both covalent ormetallic radius depending on whether theelement is a non-metal or a metal. Atomic radiican be measured by X-ray or otherspectroscopic methods. The atomic size generallydecreases across a period. It is because within the period the outerelectrons are in the same valence shell and theeffective nuclear charge increases as the atomicnumber increases resulting in the increasedattraction of electrons to the nucleus.Note that the atomic radii of noble gasesAre not considered here. Being monoatomic,Their (non-bonded radii) values are very large.In fact radii of noble gases should be comparednot with the covalent radii but with the van derWaals radii of other elements. The removal of an electron from an atom resultsin the formation of a cation, whereas gain ofan electron leads to an anion. The ionic radiican be estimated by measuring the distancesbetween cations and anions in ionic crystals.In general, the ionic radii of elements exhibitthe same trend as the atomic radii. A cation issmaller than its parent atom because it hasfewer electrons while its nuclear charge remainsthe same. The size of an anion will be largerthan that of the parent atom because theaddition of one or more electrons would resultin increased repulsion among the electronsand a decrease in effective nuclear charge. When we find some atoms and ions whichcontain the same number of electrons, we callthem isoelectronic species. For example,$O2–, F–, Na+$ and $Mg2+$ have the same number ofelectrons (10). Their radii would be differentbecause of their different nuclear charges.A quantitative measure of the tendency of anelement to lose electron is given by itsIonization Enthalpy. It represents the energyrequired to remove an electron from an isolatedgaseous atom (X) in its ground state. The ionization enthalpy is expressed inunits of kJ mol–1. We can define the secondionization enthalpy as the energy required toremove the second most loosely boundelectron The first ionization enthalpies of elementshaving atomic numbers up to 60 are plotted then The periodicity of the graph is quitestriking. You will find maxima at the noble gaseswhich have closed electron shells and verystable electron configurations. On the otherhand, minima occur at the alkali metals andtheir low ionization enthalpies can be correlated with their high reactivity. In addition, you willnotice two trends the first ionization enthalpygenerally increases as we go across a periodand decreases as we descend in a group. Electron Gain Enthalpy. when an electron is added to a neutral gaseousatom (x) to convert it into a negative ion, theenthalpy change accompanying the process isdefined as the electron gain enthalpy (∆egh).Electron gain enthalpy provides a measure ofthe ease with which an atom adds an electronto form anion. electron gain enthalpies have largenegative values toward the upper right of theperiodic table preceding the noble gases.The variation in electron gain enthalpies ofelements is less systematic than for ionizationenthalpies. As a general rule, electron gainenthalpy becomes more negative with increasein the atomic number across a period. Theeffective nuclear charge increases from left toright across a period and consequently it willbe easier to add an electron to a smaller atomsince the added electron on an average wouldbe closer to the positively charged nucleus. ElectronegativityA qualitative measure of the ability of an atomin a chemical compound to attract sharedelectrons to itself is called electronegativity.Unlike ionization enthalpy and electron gainenthalpy, it is not a measureable quantity.However, a number of numerical scales ofelectronegativity of elements viz., Pauling scale,Mulliken-Jaffe scale, Allred-Rochow scale havebeen developed. The one which is the most widely used is the Pauling scale. Electronegativity generallyincreases across a period from leftto right (say from lithium tofluorine) and decrease down a group(say from fluorine to astatine) inthe periodic table. Non-metallic elements have strong tendencyto gain electrons. Therefore, electronegativityis directly related to that non-metallicproperties of elements. It can be furtherextended to say that the electronegativity isinversely related to the metallic properties of elements. Thus, the increase inelectronegativities across a period isaccompanied by an increase in non-metallicproperties (or decrease in metallic properties)of elements. Similarly, the decrease inelectronegativity down a group is accompanied by a decrease in non-metallic properties (orincrease in metallic properties) of elements.
  1. The atomic size generally … across a period.
  1. Increases
  2. Decreases
  3. Remains Constant
  4. None of above
  1. The ionization enthalpy is expressed in units of ….
  1. $kJ mol^{–1}$
  2. $mole kJ^{-1}$
  3. $mole kJ$
  4. $-kJ mol^{-1}$
  1. Which of the following is/are numerical scales of electronegativity of elements.
  1. Pauling scale
  2. Mulliken-Jaffe scale
  3. Allred-Rochow scale
  4. All the above
  1. The … in electronegativity down a group is accompanied by a … in non-metallic properties.
  1. Increase, Decrease
  2. Decrease, Increase
  3. Decrease, Decrease
  4. Increase , Increase
  1. Electronegativity generally … across a period from left to right and … down a group in the periodic table.
  1. Increase, Decrease
  2. Decrease, Increase
  3. Decrease, Decrease
  4. Increase, Increase