Question
Read the passage given below and answer the following questions:
The f-block elements are those in which the differentiating electron enters the $(n -2)f$ orbital. There are two series of F-block elements corresponding to filling of $4f $ and $5f-$orbitals. The series of $4f-$orbitals is called lanthanides. Lanthanides show different oxidation states depending upon stability of $f^0, f^7$ and $F^{14}$ configurations, though the most conunon oxidation states is $+3$. There is a regular decrease in size oflanthanides ions with increase in atomic number which is known as lanthanide contraction.
The following questions are multiple choice questions. Choose the most appropriate answer:
The f-block elements are those in which the differentiating electron enters the $(n -2)f$ orbital. There are two series of F-block elements corresponding to filling of $4f $ and $5f-$orbitals. The series of $4f-$orbitals is called lanthanides. Lanthanides show different oxidation states depending upon stability of $f^0, f^7$ and $F^{14}$ configurations, though the most conunon oxidation states is $+3$. There is a regular decrease in size oflanthanides ions with increase in atomic number which is known as lanthanide contraction.
The following questions are multiple choice questions. Choose the most appropriate answer:
- The atomic numbers of three lanthanide elements $X, Y$ and $Z$ are $65, 68$ and $70$ respectively, their $Ln^{3+}$ electronic configuration is:
- $4f^8, 4f^{11}, 4f^{13}$
- $4f^{11}, 4f^8, 4f^{13}$
- $4f^0, 4f^2, 4f^{11}$
- $4f^3, 4f^7, 4f^9$
- Lanthanide contraction is observed in:
- $Gd$
- $At$
- $Xe$
- $Te$
- Which of the following is not the configuration oflanthanoid?
- $[Xe]4f^{10}6s^2$
- $[Xe]4f^15d^16s^2$
- $[Xe]4d^{14}5d^{10}6s^2$
- $[Xe]4f^75d^16s^2$
- Name a member of the lanthanoid series which is well known to exhibit +4 oxidation state.
- Cerium $(Z = 58)$
- Europium $(Z = 63)$
- Lanthanum $(Z = 57)$
- Gadolinium $(Z = 64)$
- Identify the incorrect statement among the following.
- Lanthanoid contraction is the accumulation of successive shrinkages.
- The different radii of $Zr$ and $Hf$ due to consequence of the lanthanoid contraction.
- Shielding power of $4f$ electrons is quite weak.
- There is a decrease in the radii of the atoms or ions as one proceeds from La to Lu.



