MCQ
The potential energy function for the force between two atoms in a diatomic molecule is approximately given by $U(x)=$ $\;\frac{a}{{{x^{12}}}} - \frac{b}{{{x^6}}}$ where a and b are constants and $x $ is the distance between the atoms. If the dissociation energy of the molecule is $D = [ U ( x = \infty) - U_{ at\ equilibrium}], D$ is
  • A
    $\frac{{{b^2}}}{{2a}}$
  • B
    $\;\frac{{{b^2}}}{{6a}}$
  • $\;\frac{{{b^2}}}{{4a}}$
  • D
    $\;\frac{{{b^2}}}{{12a}}$

Answer

Correct option: C.
$\;\frac{{{b^2}}}{{4a}}$
c
At equilibrium : $\frac{{dU(x)}}{{dx}} = 0$

$ \Rightarrow \frac{{ - 12a}}{{{x^{11}}}} = \frac{{ - 6a}}{{{x^5}}} \Rightarrow x = {\left( {\frac{{2a}}{b}} \right)^{\frac{1}{6}}}$

$\begin{gathered}
  {U_{at}}\,equilibrium = \frac{a}{{{{\left( {\frac{{2a}}{b}} \right)}^2}}} - \frac{b}{{\left( {\frac{{2a}}{b}} \right)}} \hfill \\
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\, = \frac{{{b^2}}}{{a4}}\,and\,{U_{\left( {x = \infty } \right)}} = 0 \hfill \\ 
\end{gathered} $

$\therefore $ $D = 0$$ - \left( { - \frac{{{b^2}}}{{4a}}} \right) = \frac{{{b^2}}}{{4a}}$

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

Total internal reflection can take place only if:
  1. Light goes from optically rarer medium (smaller refractive index) to optically denser medium.
  2. Light goes from optically denser medium to rarer medium.
  3. The refractive indices of the two media are close to each other.
  4. The refractive indices of the two media are widely different.
A vector $\vec A $ is rotated by a small angle $\Delta \theta$ radian $( \Delta \theta << 1)$ to get a new vector $\vec B$ In that case $\left| {\vec B - \vec A} \right|$ is
Which of the following are not a unit of time?
  1. Second.
  2. Parsec.
  3. Year.
  4. Light year.
A ball is dropped from a high rise platform at  $t=0$ starting from rest. After $6$ seconds another ball is thrown downwards from the same platform with a speed $v$. The tow ball meet at $t=18\,s$ . What is the value of $v$ ?..........$m/s$ (Take $g= 10 ms^{-2}$ )
A particle is tied to $20\, cm$ long string. It performs circular motion in vertical plane. What is the angular speed of particle when the tension in the string at the top is  zero   ......... $rad/sec$
A metre scale is moving with uniform velocity. This implies:
  1. The force acting on the scale is zero, but a torque about the centre of mass can act on the scale.
  2. The force acting on the scale is zero and the torque acting about centre of mass of the scale is also zero.
  3. The total force acting on it need not be zero but the torque on it is zero.
  4. Neither the force nor the torque need to be zero.
If the kinetic energy of a body increases by $0.1\%$, the percent increase of its momentum will be .............. $\%$
$A$ straight rod of length $L$ is released on a frictionless horizontal floor in a vertical position. As it falls $+$ slips, the distance of a point on the rod from the lower end, which follows a quarter circular locus is
The length of a metal wire is $l_1$, when the tension in it is $T_1$ and is $l_2$ when the tension is $T_2$. The unstretched length of the wire is
Work done for the process shown in the figure is ............ $J$