Question
What is meant by ‘demineralised’ water and how can it be obtained?

Answer

Demineralised water is free from all soluble mineral salts which is obtained by passing water successively through a cation exchange (in the form of $\mathrm{H}^{+}$) and an anion exchange in the form of $\mathrm{OH}^{-}$resins.
$2 \mathrm{RH}(\mathrm{~s})+\mathrm{M}^{2+}(\mathrm{aq}) \rightleftharpoons \mathrm{MR}_2(\mathrm{~s})+2 \mathrm{H}^{+}(\mathrm{aq})$
$\mathrm{H}^{+}$exchanges for $\mathrm{Na}^{+}, \mathrm{Ca}^{2+}, \mathrm{Mg}^{2+}$ and other cations present in water. This process results in release of proton which makes the water acidic.
$\mathrm{OH}^{-}$exchanges, for anions like $\mathrm{Cl}^{-}, \mathrm{HCO}_3-\mathrm{SO}_4{ }^{2-}$ etc.
$\mathrm{OH}^{-}$ions thus liberated neutralize the $\mathrm{H}^{+}$ions set free in the cation exchange process.
$\mathrm{H}^{+}(\mathrm{aq})+\mathrm{OH}^{-}(\mathrm{aq}) \longrightarrow \mathrm{H}_2 \mathrm{O}(\mathrm{l})$

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