Question
What is the effect of pressure and temperature on crystal structure?

Answer

Effect of Pressure on Crystal Structure:
Increase of pressure increases the coordination number during crystalization e.g. by applying high pressure, the NaCl crystal structure having 6 : 6 coordination changes to CsCl crystal structure having coordination number 8 : 8.
$\underset{(6: 6 \text { Coordination })}{ NaCl \text { type structure }} \xrightarrow{\text { High Temperature }} \underset{(8: 8 \text { Coordination })}{ CsCl \text { type structure }}$
Effect of Temperature on Crystal Structure :
Increase of temperature, decreases the co-ordination number e.g., on heating to 760 K CsCl structure having 8:8 coordination number changes to NaCl structure having coordination number 6 : 6.
$\underset{(8: 8 \text { Coordination })}{CsCl \text { type structure }} \xrightarrow{\text { High Temperature }} \underset{(6: 6 \text { Coordination })}{ NaCl \text { type structure }}$

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