MCQ
Which one is oxidising substance
- A${C_2}{H_2}{O_2}$
- B$CO$
- C${H_2}S$
- ✓$C{O_2}$
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$O\left( g \right) + {e^ - } \to O_{\left( g \right)}^ - \,\,\,\,;\,\,\,\,{\Delta _f}{H^\Theta } = - 141\,kJ\,mo{l^{ - 1}}$
${O^ - }\left( g \right) + {e^ - } \to O_{\left( g \right)}^{2 - }\,\,\,\,;\,\,\,\,{\Delta _f}{H^\Theta } = + 780\,kJ\,mo{l^{ - 1}}$
Thus process of formation of $O_2^-$ in gas phase is unfavourable even thought $O_2^-$ is isoelectronic with neon. It is due to the fact that,
| $Cl_2(g) \rightarrow 2Cl(g),$ | $242.3\,kJ\,mol^{-1}$ |
| $I_2(g) \rightarrow 2I(g),$ | $151.0\,kJ\,mol^{-1}$ |
| $ICl(g) \rightarrow I(g)+Cl(g),$ | $211.3\,kJ\,mol^{-1}$ |
| $I_2(s) \rightarrow I_2(g),$ | $62.76\,kJ\,mol^{-1}$ |
Given that the standard states for iodine and chlorine are $I_2(s)$ and $Cl_2(g),$ the standard enthalpy of formation for $ICl(g)$ is : ............... $\mathrm{kJ\,mol}^{-1}$
