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Question 13 Marks
Define environmental chemistry.
Answer
The environment around us is made up of chemical species which undergo chemical reactions constantly e.g., photosynthesis in plants, formation of ozone in stratosphere, etc. Environmental chemistry deals with the study of such reactions which take place in the origin, transport and life-cycle of chemical species in the environment.
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Question 23 Marks
What would have happened if the greenhouse gases were totally missing in the earth’s atmosphere? Discuss.
Answer
Earth's most abundant greenhouse gases are $\mathrm{CO}_2, \mathrm{CH}_4, \mathrm{O}_3, \mathrm{CFCs}$, and water vapour. These gases are present near the Earth's surface. They absorb solar energy that is radiated back from the surface of the Earth. The absorption of radiation results in the heating up of the atmosphere. Hence, greenhouse gases are essential for maintaining the temperature of the Earth for the sustenance of life.
In the absence of greenhouse gases, the average temperature of the Earth will decrease drastically, making it uninhabitable. As a result, life on Earth would be impossible.
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Question 33 Marks
For your agricultural field or garden you have developed a compost producing pit. Discuss the process in the light of bad odour, flies and recycling of wastes for a good produce.
Answer
While a compost pit can be a blessing for the agricultural field since it produces manure, it can also be source of trouble in the form of flies, foul odour and home for growth of bacteria, however, the negative effects can be done away with by making the pit at a place away from the residential area preferably somewhere in the field itself. Equally important is covering the pit with a suitable, lid to prevent foul odour. In such a way one can derive the benefits of a compost pit while negating the disadvantages.
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Question 43 Marks
What do you mean by green chemistry? How will it help decrease environmental pollution?
Answer
Green chemistry is a way of thinking and is about utilising the existing knowledge and principles of chemistry and other sciences to reduce the adverse effect of pollution.
For example:
  • Automobile engines have been fitted with catalytic converters which prevent the release of the vapours of hydrocarbons and oxides of nitrogen into acrolein and peroxyacetyl nitrate.
  • $\mathrm{CO}_2$ has replaced CFCs as blowing agents in the manufacture of polystyrene foam sheets.
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Question 53 Marks
Carbon monoxide gas is more dangerous than carbon dioxide gas. Why?
Answer
Carbon monoxide combines with haemoglobin to form a very stable compound known as carboxyhaemoglobin when its concentration in blood reaches 3 - 4%, the oxygen carrying capacity of the blood is greatly reduced. This results into headache, nervousness and sometimes death of the person. On the other hand $\mathrm{CO}_2$ does not combine with haemoglobin and hence is less harmful than CO.
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Question 63 Marks
How can domestic waste be used as manure?
Answer
Depending upon the nature of the waste, domestic waste can be segregated into two categories i.e., biodegradable and non–biodegradable. Biodegradable waste such as leaves, rotten food, etc. should be deposited in landfills, where they get decomposed aerobically and an aerobically into manure. Non-biodegradable waste (which cannot be degraded) such as plastic, glass, metal scraps etc. should be sent for recycling.
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Question 73 Marks
A large number of fish are suddenly found floating dead on a lake. There is no evidence of toxic dumping but you find an abundance of phytoplankton. Suggest a reason for the fish kill.
Answer
The amount of dissolved oxygen present in water is limited. The abundance of phytoplanktons causes depletion of this dissolved oxygen. This is because; phytoplanktons are degraded by bacteria present in water. For their decomposition, they require a large amount of oxygen. Hence, they consume the oxygen dissolved in water. As a result, the BOD level of water drops below 6 ppm, inhibiting the growth of fish and causing excessive fish-kill.
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Question 83 Marks
Explain the following terms:
  1. Photochemical smog.
  2. Acid rain.
  3. Eutrophication.
Answer
  1. Photochemical Smog: It is due to the formation of free radicals. They are formed when sunlight is absorbed by $\text{SO}_2$ oxides of nitrogen and hydrocarbons. They are oxidising agents.
  2. Acid Rain: Acid rain is caused by the presence of oxides of sulphur and nitrogen and $\text{CO}_2$, in the atmosphere. When pH of the rain drops below 5.6, it becomes acidic.
$\text{H}_2\text{O(l)}+\text{CO(g)}\xrightarrow{\ \ \ \ \ \ }2\text{H}^+(\text{aq})+\text{CO}_3^{2-}\text{(aq)}$
$2\text{SO}_2(\text{g})+\text{O}_2\text{(g)}+2\text{H}_2\text{O(l)}\xrightarrow{\ \ \ \ \ \ \ }2\text{H}_2\text{SO}_4(\text{aq})$
$4\text{NO}_2(\text{g})+\text{O}_2(\text{g})+2\text{H}_2\text{O(l)}\xrightarrow{\ \ \ \ \ \ \ \ }4\text{HNO}_3(\text{aq})$
The source of $\text{CO}_2$, and $\text{SO}_2$, is burning of fossil fuels, ore smelting, petroleum refining and sulphurbased industries.
Nitrogen oxides are emitted into the atmosphere mainly from automobile exhausts and fossil fuel combustion.
  1. Eutrophication: Water bodies receives large quantities of nutrients like nitrates and phosphates which helps in production of algae population. This leads to eutrophication.
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Question 93 Marks
Explain the harmful effects of oxides of sulphur and nitrogen on plants and animals.
Answer
Sulphur dioxide, $\mathrm{SO}_2$, and sulphur trioxide, $\mathrm{SO}_3$ are two basic oxide of sulphur which is known air pollutants. These oxides of sulphur are root cause for acid rain. They also cause headache, vomiting, irritation in eyes and throat in humans. They retard the growth of plants. Nitrogen dioxide, $\mathrm{NO}_2$ nitric oxide ( NO$)$ and nitrous oxide $\left(\mathrm{N}_2 \mathrm{O}\right)$ are known pollutants. These are poisnous gas which causes inflammation of lungs, reduce the rate of photosynthesis in plants and also cause acid rain and photochemical smog.
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Question 103 Marks
Describe the following in brief:
  1. Ozone depletion over Antarctica (Ozone hole) (do not write reaction).
  2. COD.
  3. Fluoride in tooth paste protects teeth against decay.
Answer
  1. Ozone depletion over Antarctica: In summer season, nitrogen dioxide and methane react with chlorine monoxide preventing ozone depletion whereas in winter, special type of clouds called polar stratospheric clouds are formed over Antarctica. These clouds provide surface on which chlorine nitrate molecules formed gets hydrolysed to form HOCI. It also reacts with HCl to give $Cl_2$. When sunlight returns to Antarctica, again ozone depletion starts by free radicals.
  2. COD: It is the amount of oxygen (in ppm) required to oxidise the contaminants. COD is determined by using chemical oxidising agent $K_2Cr_2O_2​​​​​​​$​​​​​​​.
  3. It converts hydroxyapapite (enamel on the surface of teeth) into much harder fluorapatite and thus prevents tooth decay.
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Question 113 Marks
For dry cleaning, in the place of tetrachloroethane, liquefied carbon dioxide with suitable detergent is an alternative solvent. What type of harm to the environment will be prevented by stopping use of tetrachloroethane? Will use of liquefied carbon dioxide with detergent be completely safe from the point of view of pollution? Explain.
Answer
Solvents used to dry clean clothes are usually chlorinated compounds such as tetra chloroethylene $\left(\mathrm{CCl}_2=\mathrm{CCl}_2\right)$ which is a potential human carcinogen. These chlorinated compounds also have serious environmental consequences such as greenhouse effect, ozone depletion, water pollution, etc. The use of liquefied carbon dioxide with a suitable detergent for dry cleaning will not be completely safe from the point of view of pollution but will be less harmful.
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Question 123 Marks
A factory was started near a village. Suddenly villagers started feeling the presence of irritating vapours in the village and cases of headache, chest pain, cough, dryness of throat and breathing problems increased. Villagers blamed the emissions from the chimney of the factory for such problems. Explain what could have happened. Give chemical reactions for the support of your explanation.
Answer

The symptoms observed in the villagers show that oxides of nitrogen and sulphur must be coming out of the chimney. This is due to combustion of fossil fuels like coal, oil, natural gas, gasoline, etc. to produce high temperatures at which oxidation of atmospheric nitrogen takes place forming $NO$ and $NO_2$:

$\mathrm{SO}_2$ is produced due to combustion of sulphur containing coal and fuel oil or roasting of sulphide ores like iron pyrites $\left(\mathrm{FeS}_2\right)$, copper pyrites $\left(\mathrm{CuFeS}_2\right)$, etc.
$\mathrm{Cu}_2 \mathrm{~S}+\mathrm{O}_2 \rightarrow 2 \mathrm{Cu}+\mathrm{SO}_2$
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Question 133 Marks
What is the importance of measuring BOD of a water body?
Answer
BOD is the measure of level of pollution caused by organic biodegradable material in terms of how much oxygen will be required to break down the organic material biologically. Clean water would have BOD values less than 5 ppm while highly polluted water could have a BOD value of 17 ppm or more.
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Question 143 Marks
  1. How does Eutrophication occur?
  2. Write any two adverse effect of lead pollution.
Answer
  1. Nutrients of many fertilizers like phosphates and nitrates are main cause of eutrophication. They usually enter lake through streams. In the presence of these nutrients, the population of algae increases. Since this algae provide food supply, the population of many aquatic animals increases which leads to decrease in dissolved oxygen.
  2.  
  1. It causes inhibition of enzymatic activity.
  2. Lead effects impairment of kidney function and neurological disorder.
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Question 153 Marks
  1. Name two important sinks of $\mathrm{CO}_2$.
  2. What is marine pollution?
  3. What is humification?
Answer
  1. Soil micro-organisms convert $\mathrm{CO}_2$ into carbonates. Sea water can dissolve large amount of $\mathrm{CO}_2$​​​​​​​.
  2. Marine pollution is pollution caused by undesirable substances in sea water e.g., spilling of oils from ships.
  3. Humification is production of humus by microorganisms in soil. It increases fertility of soil.
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Question 163 Marks
  1. Discuss the harmful effects of photochemical smog.
  2. Write any two effects of acid rain.
  3. Define soil pollution.
Answer
  1. The compounds present in photochemical smog are ozone and PAN. They cause irritation in eyes and other respiratory problems. $\mathrm{NO}_2$ gives off brown colour to smog and reduce the visibility.
  2.  
  1. Acidification of soil leads to decrease in fertility of soil and retardation in growth of plants.
  2. It causes corrosion of steal products, metallic and marble structures.
  1. Soil pollution can be define as addition of unwanted substances which affect its physical, chemical and biological characteristics and reduces its fertility and productivity.
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Question 173 Marks
Why does water covered with excessive algal growth become polluted?
Answer
Water containing algae have a very less amount of oxygen as the algae consume most of the oxygen dissolved in the water, and thus deprive aquatic plants and oxygen of it, and hence kill them. This results in eventual loss of biodiversity and thus, the balance of nature is broke. This is a kind of pollution it makes happen.
This condition is called- Eutrophication.
Some algae even produce toxins that are harmful to higher forms of life.
P.S.- Algae are formed mostly by addition of chemical fertilisers containing phosphates, which enhance algae growth)
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Question 183 Marks
What could be the harmful effects of improper management of industrial and domestic solid waste in a city?
Answer
The improper disposal of wastes os one of the major caises of environment pollution. If domestic waste is not properly managed, it may go to sewers or may be eaten by cattle. Non-biodegradable wastes like, metals, glass, polythene etc, may choke the sewers or gut of the ruminants. Polythene bags if swallowed by cattle may result in their death. Similarly, if industrial waste is not properly managed it will lead to air, water and soil pollution.
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Question 193 Marks
Ozone is a gas heavier than air. Why does ozone layer not settle down near the earth?
Answer
In stratosphere, the formation of $\mathrm{O}_3$ goes on continuously, but $\mathrm{O}_3$ is also decomposed by UV-radiation between 240 to 360nm.
$\text{O}_3+\text{h}\upsilon\xrightarrow{ \ \ \ (240-360\text{nm}) \ \ \ }\text{O}_2+\text{O}$
The O -atom reacts with second $\mathrm{O}_3$ molecule. $\mathrm{O}_3+\mathrm{O} \rightarrow 2 \mathrm{O}_2$ Net reaction $2 \mathrm{O}_3 \rightarrow 3 \mathrm{O}_2$ Thus, the reactions form a delicate balance in which the rate of $\mathrm{O}_3$ decomposition matches the rate of $\mathrm{O}_3$ formation, i.e., a dynamic equilibrium exists and maintains a constant concentration of $\mathrm{O}_3$.
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Question 203 Marks
How oxides of nitrogen are generated? What are harmful effects of oxides of nitrogen?
Answer
Oxides of Nitrogen: NO is not considered to have a significant adverse effect on human health, even at elevated concentrations. It is oxidised by oxygen and even more rapidly by ozone, to nitrogen dioxide which is extremely toxic to living tissues and harmful to paints, textiles and metals.
$\text{N}_2(\text{g})+\text{O}_2\text{(g)}\xrightarrow{\ \ \ 1483\text{K}\ \ \ }2\text{NO(g)}$
$2\text{NO(g)}+\text{O}_2\text{(g)}\xrightarrow{\ \ \ \ \ \ \ \ \ }2\text{NO}_2(\text{g})$
$\text{NO(g)}+\text{O}_3(\text{g})\xrightarrow{\ \ \ \ \ \ \ \ \ \ }\text{NO}_2(\text{g})+\text{O}_2(\text{g})$
Eventually, $\mathrm{NO}_2$ is oxidised to nitrate, $\mathrm{NO}_3^{}{-}$ion, and washed into the soil where it serves as fertilizer. The oxides of nitrogen are second most abundant atmospheric pollutants.
Harmful effects:
  1. NO depletes ozone layer.
  2. $\mathrm{NO}_2$ causes acid rain.
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Question 213 Marks
During an educational trip, a student of botany saw a beautiful lake in a village. She collected many plants from that area. She noticed that villagers were washing clothes around the lake and at some places waste material from houses was destroying its beauty.
After few years, she visited the same lake again. She was surprised to find that the lake was covered with algae, stinking smell was coming out and its water had become unusable.Can you explain the reason for this condition of the lake?
Answer
Disposing of waste material and washing clothes in lake water makes the water rich in nutrients like phosphate. It enhances algae growth. Such profuse algal growth covers the water surface which reduces oxygen concentration in water. This leads to anaerobic conditions with accumulation of dead and decaying water animals, thus, leaving the water with stinking smell and making it unusable.
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Question 223 Marks
  1. What are the reactions involved in removing $\text{SO}_2$ from the atmosphere by passing it through a solution containing citrate ions?
  2. What is the most important sink of CO pollutant?
  3. How are fuel gases from industries freed from oxides of nitrogen and sulphur?
Answer
  1. $\text{SO}_2\text{(g)}+\text{H}_2\text{O(l)}\rightleftharpoons\text{HSO}^-_3(\text{aq})+\text{H}^+(\text{aq})$
$\text{HSO}^-_3+\text{H}_2\text{Cit}^-\xrightarrow{\ \ \ \ \ \ \ \ }(\text{SO}_3.\text{H}_2\text{Cit})^{2-}$
  1. Soil microorganisms.
  2. By scrubbing them with conc. $\mathrm{H}_2 \mathrm{SO}_4$ or with alkaline solutions like $\mathrm{Ca}(\mathrm{OH})_2$ and $\mathrm{Mg}(\mathrm{OH})_2$.
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Question 233 Marks
Oxidation of sulphur dioxide into sulphur trioxide in the absence of a catalyst is a slow process but this oxidation occurs easily in the atmosphere. Explain how does this happen. Give chemical reactions for the conversion of $\mathrm{SO}_2$ into $\mathrm{SO}_3$.
Answer
The presence of particulate matter in polluted air catalyses the oxidation of $\mathrm{SO}_2$ to $\mathrm{SO}_3$.The reaction is also promoted by ozone and hydrogen peroxide.
$2\text{SO}_2+\text{O}_2\xrightarrow{ \ \ \ \ \text{Dust or soot particles} \ \ }2\text{SO}_3$
$\text{SO}_2+\text{O}_3\xrightarrow{ \ \ \ \ \text{h}\upsilon \ \ }2\text{SO}_3+\text{O} _2$
$\text{SO}_2+\text{H}_2\text{O}_2\xrightarrow{ \ \ \ \ \ \ }\text{H}_2\text{O}+\text{SO}_3$
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Question 243 Marks
How is ozone produced in stratosphere?
Answer
Ozone in the stratosphere is a product of UV radiations acting on dioxygen ($\mathrm{O}_2$) molecules. The UV raditions split apart moleculer oxygen into free oxygen (O) atoms, These oxygen atoms combine with molecular oxygen to form ozone.
$\text{O}_2\text{(g)}\xrightarrow{ \ \ \ \text{UV} \ \ \ }\text{O}\text{(g)}+\text{O}\text{(g)}$
$\text{O}\text{(g)}+\text{O}_2\text{(g)}\overset{\text{uv}}{\rightleftarrows}\text{O}_3\text{(g)}$
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Question 253 Marks
From where does ozone come in the photochemical smog?
Answer
When fossil fuels are burnt, nitric oxide and hydrocarbons from unburnt fuels are produced. In sunlight, nitric oxide is converted to nitrogen dioxide. $\mathrm{NO}_2$ absorbs energy from sunlight and breaks up into NO and free oxygen atoms which are very reactive and combine with $\mathrm{O}_2$ to form $\mathrm{O}_3$, which reacts with NO to form $\mathrm{NO}_2$ and $\mathrm{O}_2$.
$\text{NO}_2\xrightarrow{ \ \ \ \ \text{h}\upsilon\ \ \ }\text{NO}+\text{O}$
$\text{O}+\text{O}_2+\rightleftharpoons\text{O}_3$
$\text{NO}+\text{O}_3\xrightarrow{ \ \ \ \ \ \ \ }\text{NO}_2+\text{O}_2$
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Question 263 Marks
What are the sources of dissolved oxygen in water?
Answer
Oxygen reaches water either through atmosphere or from the process of photosynthesis carried out by many aquatic green plants during day light. However, during night, photosynthesis stops but the plants continue to respire, resulting in reduction of dissolved oxygen. The dissolved oxygen is also used by microorganisms to oxidize organic matter.
In brief, sources of dissolved oxygen in water are:
  1. Photosynthesis by aquatic plants.
  2. Due to the direct contact of water surface with air.
  3. Mechanical aeriation.
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Question 273 Marks
  1. Write two toxic effects of mercury contamination.
  2. Why does sea level rise due to global warming?
Answer
  1.  
  1. Mercury inhibits the catalysis of general metabolic reaction because it combines with many enzymes.
  2. It damages the neurons of nervous system in the brain.
  1. Global warming leads to rise in seal level because with increase in temperature, melting of glaciers takes place. It is one of the outcome of global warming.
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Question 283 Marks
A farmer was using pesticides on his farm. He used the produce of his farm as food for rearing fishes. He was told that fishes were not fit for human consumption because large amount of pesticides had accumulated in the tissues of fishes. Explain how did this happen?
Answer
Pesticides are organic compounds which are used to protect plants from pests. These are mild poisons. These pesticides stick to the plants and also flow into lakes along with the rain water. Rearing fishes when consume these plants as their food the poisonous pesticides accumulate in the tissues of fishes. Thus, these fishes are not fit for human consumption.
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