$Ag+ I^- \rightarrow AgI +e^-,$ $E^o = 0.152\, V$
$Ag \rightarrow Ag^+ +e^-,$ $E^o =-0.800\, V$
$AgI$ માટે log $K_{sp}$નું મૂલ્ય શું થશે ? $(2. 303\, RT/F= 0. 059\, V)$
$E^{\circ}=-0.800\, V$
$(ii)$ $A g+\mathrm{I}^{-} \rightarrow A g \mathrm{I}+e$
$E^{\circ}=0.152\, V$
From ( $i$ ) and $(ii)$ we have,
$A g \mathrm{I} \rightarrow A g^{+}+\mathrm{I}$
$E^{\circ}=-0.952\, V$
$E_{c e l l}^{\circ}=\frac{0.059}{n} \log K$
$\therefore-0.952=\frac{0.059}{1} \log \left[A g^{+}\right]\left[\mathrm{I}^{\mathrm{I}}\right]$
[as $k=\left[A g^{+}\right]\left[\mathrm{I}^{-}\right]$
$\quad-\frac{0.952}{0.059}=\log K_{s p}$
$\quad-16.13=\log K_{s p}$
$Mn^{2+} +2e- \rightarrow Mn;\, E^o = -1.18\,V$
$2(Mn^{3+} +e^- \rightarrow Mn^{2+} )\,;\,E^o=+1.51\,V$
તો $3Mn^{2+} \rightarrow Mn+ 2Mn^{3+}$ માટે $E^o$ કેટલો થશે ?
$Cr_{(s)} | Cr^{3+}_{(0.1\,M)} | | Fe^{2+}_{(0.01\,M)} | Fe;$
$E^0_{{cr}^{3+} |Cr} = -0.72 \,V,$ $ E^{0}_{{Fe}^{2+}{| Fe}}$ $= -0.42 \,V$
$Zn\,(s)\,\, + \,\,C{u^{2 + }}\,(aq)\, \rightleftharpoons \,Z{n^{2 + \,}}\,(aq)\, + Cu\,(s)$
$(R = 8 \,JK^{-1}\,mol^{-1},\, F = 96000\,C\,mol^{-1})$