$Zn_{(s)} + Ag_2O_{(s)} + H_2O_{(l)} \rightleftharpoons $$2Ag_{(s)} + Zn^{2+}_{(aq)}+ 2OH^-_{(aq)}$
જો અર્ધકોષ પોટેન્શિયલ
$Zn^{2+}_{(aq)} + 2e^- \rightarrow Zn_{(s)}\,;\,\, E^o = - 0.76\, V$
$Ag_2O_{(s)} + H_2O_{(l)} + 2e^- \rightarrow 2Ag_{(s)} + 2OH^-_{(aq)}\,,$$E^o = 0.34\, V$
હોય, તો કોષ-પોટેન્શિયલ ......... $V$ થશે.
$Zn | Zn ^{2+}(0.1\, M ) \| Ag ^{+}(0.01 \,M )| Ag$
[આપેલ $: E_{Z n^{+2}/Z_{n}}^{0}=-0.76 \,V ; E _{A g^{+} / A_{ g }}^{0}=+0.80 \,V ; \frac{2.303 RT }{ F }=0.059$]
$\lambda_{\mathrm{m}\left(\mathrm{H}_{2} \mathrm{SO}_{4}\right)}^{0}=\mathrm{x} \;\mathrm{S}\; \mathrm{cm}^{2} \mathrm{mol}^{-1}$
$\lambda_{\mathrm{m}\left(\mathrm{K}_{2} \mathrm{SO}_{4}\right)}^{0}=\mathrm{y} \;\mathrm{S\;cm}^{2} \mathrm{mol}^{-1}$
$\lambda_{\mathrm{m}(\mathrm{CH_3} \mathrm{COOK})}^{0}=\mathrm{z}\; \mathrm{S\;cm}^{2} \mathrm{mol}^{-1}$
$\mathrm{CH}_{3} \mathrm{COOH}$ માટે $\lambda_{\mathrm{m}}^{0}\left(\mathrm{in}\; \mathrm{S} \;\mathrm{cm}^{2} \mathrm{mol}^{-1}\right)$ શું હશે ?