Among ethanol, dimethyl ether, methanol and propanal, the isomers are$:$
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Ethanol $\ce{(C_2H_5OH)}$ and dimethyl ether $\ce{(CH_{3}−O−CH_3)}$ have same molecular formula but different functional groups, so they are isomers.
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The high boiling point of ethanol $(78.2^\circ C)$ compared to dimethyl ether $(−23.6^\circ C),$ though both having the same molecular formula $C_2H_6O,$ is due to: