\(y \) ના મોલ- અંશ \({X_B} = \frac{3}{{1 + 3}} = \frac{3}{4}\)
\({\text{P}}\) કુલ \({\text{ = }}{{\text{p}}_{\text{A}}}^{\text{0}}{{\text{X}}_{\text{A}}}{\text{ + }}{{\text{p}}_{\text{B}}}^{\text{0}}{{\text{X}}_{\text{B}}}\,\)
\( \Rightarrow \,\,\,{\text{P}}\) કુલ \( = \frac{{{P_A}^0}}{4} + \frac{{{P_B}^0}}{5}\)
\(\therefore \,\,550 = \frac{{{p_A}^0 + 3p{B^0}}}{4}\,\,\,\)
\(\therefore \,\,\,{{P}^{0}}_{A}\text{+ 3}{{\text{p}}_{\text{B}}}^{\text{0}}\text{ = 550 }\times \,\,\text{4}\,\text{=}\,\text{2200}\) ............... \((1)\)
\(y \) નો \(1 \) મોલ ઉમેરતા, \(\,{\text{P}}\) કુલ \({\text{ = }}{{\text{p}}_{\text{A}}}^{\text{0}}{{\text{X}}_{\text{A}}}{\text{ + }}{{\text{p}}_{\text{B}}}^{\text{0}}{{\text{X}}_{\text{B}}}\,\)
\(\therefore 560 = \frac{{{P_A}^0}}{5} + \frac{{4{p_B}^0}}{5}\)
\({X_A} = \frac{1}{{1 + 4}} = \frac{1}{5},\,\,\,\,\,\,{X_B} = \frac{4}{{1 + 4}} = \frac{4}{5}\)
\(\therefore {\text{ }}{{\text{p}}_{\text{A}}}^{\text{0}}{\text{ + 4}}{{\text{p}}_{\text{B}}}^{\text{0}}{\text{ = 560 }} \times {\text{ 5}}\,\,\)
\(\therefore \text{ }{{\text{p}}_{\text{A}}}^{\text{0}}\text{+ 4}-{{\text{p}}_{\text{B}}}^{\text{0}}\,\text{=}\,\,\text{2800}\) .............................. \((2)\)
પરિણામ \((2)\) - પરિણામ \( (1)\) કરતાં
\(\therefore \,\,{{\text{p}}_{\text{A}}}^0 + 4{p_B}^0\, - \,{p_A}^0 - 3{p_B}^0 = 2800 - 2200\)
\(\therefore {\text{ }}{{\text{p}}_{\text{B}}}^{\text{0}}{\text{ = 600}}\) મિમી
\({\text{ }}\therefore {\text{ }}{{\text{p}}_{\text{A}}}^{\text{0}}{\text{ = 400 }}\) મિમી
(યુરિયા અને ગ્લુકોઝનો અણુભાર અનુક્રમે $60$ અને $180$ છે.)
(યુરિયાનો અણુભાર $= 60\, g\, mol^{-1}$)