Question
Explain the electrophilic substitution reactions of amine.
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Vapour pressures of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot $p_{\text {total }}, p_{\text {chloroform }}$ and $p_{\text {acetone }}$ as a function of $x_{\text {acetone }}$ The experimental data observed for different compositions of mixture is :
Plot this data also on the same graph paper. Indicate whether it has positive deviation or negative deviation from the ideal solution.
→| $100 \times x_{\text {acetone }}$ | 0 | 11.8 | 23.4 | 36.0 | 50.8 | 58.2 | 64.5 | 72.1 |
| $p_{\text {acetone }} / mm Hg$ | 0 | 54.9 | 110.1 | 202.4 | 322.7 | 405.9 | 454.1 | 521.1 |
| $p_{\text {chloroform }} / mm Hg$ | 632.8 | 548.1 | 469.4 | 359.7 | 257.7 | 193.6 | 161.2 | 120.7 |
Describe the common name system and IUPAC system of naming amines.
Explain Kohlrausch's law of independent migration of ions. Mention the application of Kohlrausch's law.
Explain the structure and classification of animes.
$\ce{[NIC14]^{2-}}$ is paramagnetic while $\ce{[Ni(CO)_4]}$ is diamagnetic though both are tetrahedral. Why?
→What is called a battery? Explain its characteristics and describe dry cell and mercury cell.
Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory :
(i) $\left[ Fe ( CN )_6\right]^{4-}$
(ii) $\left[ FeF _6\right]^{3-}$
(iii) $\left[ Co \left( C _2 O _4\right)_3\right]^{3-}$
(iv) $\left[ CoF _6\right]^{3-}$
→(i) $\left[ Fe ( CN )_6\right]^{4-}$
(ii) $\left[ FeF _6\right]^{3-}$
(iii) $\left[ Co \left( C _2 O _4\right)_3\right]^{3-}$
(iv) $\left[ CoF _6\right]^{3-}$
Write short notes :
Ammonolysis
Ammonolysis
Identify A and B in the following reactions:
- $\text{C}_2\text{H}_5\text{OH}\xrightarrow{\text{Cu},573\text{k}}\text{A}\xrightarrow{\text{CH}_3\text{MgBr}}\text{B}\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{H}_2\text{O}/\text{H}^{+}$
Explain the oxidation of primary, secondary and tertiary alcohols.