Question
Explain the mechanism of rusting of iron.

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(a) Write the principle of manufacture of sulphuric acid by contact process.###(b) Write the reaction of concentrated sulphuric acid with oxalic acid.
Describe how does the enthalpy of reaction remain unchanged when a catalyst is used in the reaction.
Graphically explain the effect of temperature on the rate constant of reaction. How can this temperature effect on rate constant be represented quantitatively?
$\ce{[NIC14]^{2-}}$ is paramagnetic while $\ce{[Ni(CO)_4]}$ is diamagnetic though both are tetrahedral. Why?
i. Give reasons :
a. Although $- \ce{NH2}$ group is o/p directing in electrophilic substitution reactions, yet aniline, on nitration gives good yield of $m-$nitroaniline.
b. $(\ce{CH 3)2NH}$ is more basic than $(\ce{CH3)3N}$ in an aqueous solution.
c. Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
ii. Distinguish between the following:
a. $\ce{CH 3 CH 2 NH 2}$ and $(\ce{CH 3 CH 2)2NH}$
b. Aniline and $\ce{CH3NH2}$
Explain the cyclic structure of glucose.
  1. What is meant by:
  1. Colligative properties.
  2. Molality of a solution.
  1. What concentration of nitrogen should be present in a glass of water at room temperature ? Assume a temperature of $25^\circ C,$ a total pressure of $1$ atmosphere and mole fraction of nitrogen in air of $0.78. [K_H $ for nitrogen $= 8.42 x 10^{–7}\ M/mm\ Hg].$
Derive a formula to determine the molar mass of a solute by depression of freezing point.
Match the property given in Column $I$ with the element given in Column $II.$
 
Column $I ($Property$)$
 
Column $II ($Element$)$
$(i)$
Lanthanoid which shows $+4$ oxidation state
$(a)$ $Pm$
$(ii)$
Lanthanoid which can show $+2$ oxidation state
$(b)$ $Ce$
$(iii)$
Radioactive lanthanoid
$(c)$ $Lu$
$(iv)$
Lanthanoid which has $4f^7$ electronic configuration in $+3$ oxidation state
$(d)$ $Eu$
$(v)$
 Lanthanoid which has $4f^{14}$ electronic configuration in $+3$ oxidation state
$(e)$ $Gd$
 
 
$(f)$ $Dy$
Answer the following questions.
Comment on the specificity of enzyme action. What is the most important reason for their specificity?