Question
Explain why elemental semiconductor cannot be used to make visible LEDs.

Answer

Specially designed diodes, which give out light rediations when forward biases. LED's are made of GaAsp, Gap etc.
There are forwad biased P-N junctions which emits spontaneous fadiation. In elemental semiconductor, the band gap is such that the emission are in infrared region and not in visible region. $\lambda=\frac{\text{hc}}{\text{E}_\text{g}}$ For Si; $\text{E}_\text{g}= 1.1\text{eV},\lambda=\frac{1242}{1.1}=1129\text{nm}$ For Ge; $\text{E}_\text{g}=0.7\text{eV},\lambda=\frac{1242}{0.7}=1725\text{nm}$

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