$k=\frac{2.303}{t} \log \frac{a}{a-x}$
Where, $k=$ Rate constant
$a=$ initial concentration
$a-x=$ concentration after time ${ }^{\prime} t^{\prime}$
For half-life, $t=t_{1 / 2}, x=\frac{a}{2}$
On substituting the values, we get
$k=\frac{2.303}{t_{1 / 2}} \log \frac{a}{a-\frac{a}{2}}=\frac{2.303}{t_{1 / 2}} \log 2$
$=\frac{0.693}{t_{1 / 2}}$
$k=\frac{0.693}{t_{1 / 2}}$
Thus, $t_{1/2}$ of a first order reaction does not depend upon the concentration.
$2NO \rightleftharpoons {N_2}O + \left[ O \right]$
${O_3} + \left[ O \right] \to 2{O_2}\,(slow)$
તો પ્રકિયાનો કમ જણાવો.
