$(I)\, [Ni(CN)_4]^{2-}\,\,\,(II)\, [NiCl_4]^{2-}\,\,\,(III)\,Ni(CO_4)\,\,\,$
$(IV)\, [Ni(H_2O)_6 ]^{2+}$
\(\left[ NiCl _4\right]^{2-}\) and \(\left[ Ni ^2\left( H _2 O \right)_6\right]^{2+}\) contain 2 unpaired electrons each. Thus they are paramagnetic and will be attracted by the magnetic field.
In \(\left[ Ni ( CN )_4\right]^{2-}\) and \(\left[ Ni ( CO )_4\right]\), all the electrons are paired. Hence, they are diamagnetic substances and are not attracted by the magnetic field.
| કૉલમ$-I$ | કૉલમ$-II$ |
| $(a)\;Co^{+3}$ | $(i)\;\sqrt{8}\; B.M.$ |
| $(b)\;Cr^{+3}$ | $(ii)\;\sqrt{35}\; B.M.$ |
| $(c)\;Fe^{+3}$ | $(iii)\;\sqrt{3}\; B.M.$ |
| $(d)\;Ni^{+2}$ | $(iv)\;\sqrt{24}\; B.M.$ |
| $(v)\;\sqrt{15}\; B.M.$ |
$(a)\quad (b)\quad (c)\quad (d)$
(પ.ક્ર.: $Mn\, = 25, Co\, = 27, Ni\, = 28, Zn\, = 30$)