==> \(\frac{{{K_1}A({\theta _A} - {\theta _C})}}{l} = \frac{{{K_2}A({\theta _C} - {\theta _B})}}{l}\)
==> \(\frac{{{\theta _A} - {\theta _C}}}{{{\theta _C} - {\theta _B}}} = \frac{{{K_2}}}{{{K_1}}}\)...\((i) \)
Also \({\left( {\frac{Q}{t}} \right)_{AD}} = {\left( {\frac{Q}{t}} \right)_{DB}}\)
==>\(\frac{{{K_3}A({\theta _A} - {\theta _D})}}{l} = \frac{{{K_4}A({\theta _D} - {\theta _B})}}{l}\)
==>\(\frac{{{\theta _A} - {\theta _D}}}{{{\theta _D} - {\theta _B}}} = \frac{{{K_4}}}{{{K_3}}}\) ..\(.(ii)\)
It is given that \({\theta _C} = {\theta _D},\) hence from equation \((i)\) and \((ii)\) we get \(\frac{{{K_2}}}{{{K_1}}} = \frac{{{K_4}}}{{{K_3}}}\) ==> \({K_1}{K_4} = {K_2}{K_3}\)