$H_2O _{(g)} + C_{(s)} = CO_{(g)} + H_{2{(g)}}$; $\Delta H = 131\, KJ$, $CO_{(g)} + \frac{1}{2}\,O_{2{(g)}} = CO_2$$_{(g)}$ ; $\Delta H = -282\, KJ,H_2$ $_{(g)}$$+ \frac{1}{2}\,O_2$$_{(g)}$ $= H_2O$$_{(g)}$; $\Delta H = - 242\, KJ, $ $C_{(s)}$ $+ O_2$ $_{(g)}$ $= $ $ CO_2$ $_{(g)}$; $\Delta$ $H = - x\,\,KJ$

$  C(s)\,\, + \,\,{O_2}(g)\,\, \to \,\,C{O_2}\,(g)$         $\Delta H  = \,\, - \,94\,\,kcal$

${H_2}\,(g)\,\, + \,\,\frac{1}{2}\,{O_2}\,(g)\,\, \to \,\,{H_2}O\,(g),$  $\Delta H\,\, = \,\, - \,68\,\,kcal$

${C_2}{H_5}OH\,(\ell )\,\, + \,\,3{O_2}\,(g)\,\, \to \,\,2C{O_2}\,(g)\,\, + \,\,3{H_2}O\,(\ell ),$$\Delta H\,\, = \,\,\, - \,327\,\,kcal$