b
${(\Delta Q)_P} = \mu {C_P}\Delta T$
$\Rightarrow$ $2 \times {C_P} \times (35 - 30)$
$\Rightarrow$ ${C_P} = 7\frac{{cal}}{{mole{\rm{ - }}K}}$
$\because$ ${C_P} - {C_V} = R$
$\Rightarrow$ ${C_V} = {C_P} - R = 7 - 2 = 5\frac{{cal}}{{mole{\rm{ - }}kevin}}$
$\therefore$ ${(\Delta Q)_V} = \mu {C_V}\Delta T = 2 \times 5 \times (35 - 30) = 50\,cal.$