અષ્ટફલકીય સંકીર્ણની મોલર આયનિય વાહકતા:

$(i)$ $PtCl _{4} . 5 NH _{3}$

$(ii)$ $PtCl _{4} . 4 NH _{3}$

$(iii)$ $PtCl _{4} . 3 NH _{3}$

$(iv)$ $PtCl _{4}. 2 NH _{3}$

ક્યા ક્રમને અનુસરે છે?

Q: અષ્ટફલકીય સંકીર્ણની મોલર આયનિય વાહકતા: $(i)$ $PtCl _{4} . 5 NH _{3}$ $(ii)$ $PtCl _{4} . 4 NH _{3}$ $(iii)$ $PtCl _{4} . 3 NH _{3}$ $(iv)$ $PtCl _{4}. 2 NH _{3}$ ક્યા ક્રમને અનુસરે છે?

d The reaction for $PtCl _{4} \cdot 5 NH _{3}$, is given as, $\left[ Pt \left( NH _{3}\right)_{5} Cl \right] Cl _{3} \rightarrow\left[ Pt \left( NH _{3}\right)_{5} Cl \right]^{3+}+3 Cl ^{-}(4$ ions $)$ Reaction for $PtCl _{4} \cdot 4 NH _{3}$ is given as, $\left[ Pt \left( NH _{3}\right)_{4} Cl _{2}\right] Cl _{2} \rightarrow\left[ Pt \left( NH _{3}\right)_{4} Cl _{2}\right]^{2+}+2 Cl ^{-}(3$ ions $)$ Reaction for $PtCl _{4} \cdot 3 NH _{3}$ is given as, $\left[ Pt \left( NH _{3}\right)_{3} Cl _{3}\right] Cl \rightarrow\left[ Pt \left( NH _{3}\right)_{3} Cl _{3}\right]^{2+}+ Cl ^{-}(2 \text { ions })$ Reaction for $PtCl _{4} \cdot 2 NH _{3}$ is given as, $\left[ Pt \left( NH _{3}\right)_{2} Cl _{4}\right]$ Non-ionic $(0$ ions $)$

Question

અષ્ટફલકીય સંકીર્ણની મોલર આયનિય વાહકતા:

$(i)$ $PtCl _{4} . 5 NH _{3}$

$(ii)$ $PtCl _{4} . 4 NH _{3}$

$(iii)$ $PtCl _{4} . 3 NH _{3}$

$(iv)$ $PtCl _{4}. 2 NH _{3}$

ક્યા ક્રમને અનુસરે છે?

A$i < ii < iii < iv$
B$iv < iii < i < ii$
C$iii < iv < ii < i$
D$iv < iii < ii < i$

AIIMS 2019, Medium

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Solution

d
The reaction for $PtCl _{4} \cdot 5 NH _{3}$, is given as,

$\left[ Pt \left( NH _{3}\right)_{5} Cl \right] Cl _{3} \rightarrow\left[ Pt \left( NH _{3}\right)_{5} Cl \right]^{3+}+3 Cl ^{-}(4$ ions $)$

Reaction for $PtCl _{4} \cdot 4 NH _{3}$ is given as,

$\left[ Pt \left( NH _{3}\right)_{4} Cl _{2}\right] Cl _{2} \rightarrow\left[ Pt \left( NH _{3}\right)_{4} Cl _{2}\right]^{2+}+2 Cl ^{-}(3$ ions $)$

Reaction for $PtCl _{4} \cdot 3 NH _{3}$ is given as,

$\left[ Pt \left( NH _{3}\right)_{3} Cl _{3}\right] Cl \rightarrow\left[ Pt \left( NH _{3}\right)_{3} Cl _{3}\right]^{2+}+ Cl ^{-}(2 \text { ions })$

Reaction for $PtCl _{4} \cdot 2 NH _{3}$ is given as,

$\left[ Pt \left( NH _{3}\right)_{2} Cl _{4}\right]$ Non-ionic $(0$ ions $)$

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