If $\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}(=+0.77 \mathrm{V})$ is greater than that of $I_{2} / 2 \mathrm{I}^{-}(=0.536 \mathrm{V}),$ Fe $^{3+}$ will be reduced to $\mathrm{Fe}^{2+}$ and $I^-$ will be oxidised to $I_2$.
$\mathrm{BrO}_{4}^{-} \stackrel{1.82 \mathrm{V}}{\longrightarrow} \mathrm{BrO}_{3}^{-} \stackrel{1.5 \mathrm{V}}{\longrightarrow} \mathrm{HBrO}$$\stackrel{1.0652 \mathrm{V}}{\longrightarrow} \mathrm{Br}_{2} \stackrel{1.595 \mathrm{V}}{\longrightarrow} \mathrm{Br}^{-}$
તો વિષમપ્રમાણ (disproportionation) અનુભવતો ઘટક ............
$2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{O}_{2}+4 \mathrm{H}^{\oplus}+4 \mathrm{e}^{-} ; \mathrm{E}_{\mathrm{red}}^{0}=1.23 \mathrm{V}$ અને $ - 5 \times {10^{ - 4}}\,V\,{K^{ - 1}}$ છે. કોષપ્રક્રિયા $(\mathrm{R}=8.314 \;\mathrm{J} \mathrm{mol}^{-1} \mathrm{K}^{-1} ; \text { Temperature }=298 \;\mathrm{K} ;$ ઓક્સિજન એ પ્રમાણિત વાતાવરણ દબાણ $1$ બાર હેઠળ છે)