d
For $A:$
$\frac{C_{p}}{C_{v}}=\gamma=1+\frac{2}{f}=\frac{29}{22}$
It gives $f=6.3 \approx 6 \quad(3 \text { translational, } 2 \text { rotational and } 1$ vibrational)
For $B:$
$\frac{C_{p}}{C_{v}}=\gamma=1+\frac{2}{f}=\frac{30}{21}$
$\Rightarrow \mathrm{f}=4.67$
$\Rightarrow \quad \approx 5 \quad(3 \text { translational, } 2$ rotational, no vibrational)