$\mathrm{W}=\mathrm{P} \Delta \mathrm{V}=\mathrm{n} \mathrm{R} \Delta \mathrm{T}$
But $Q=n C_{p} \Delta T=n \frac{\gamma R}{r-1}$
$\Rightarrow \quad W=Q\left(\frac{\gamma-1}{r}\right)=100\left(\frac{1.4-1}{1.4}\right)=28.57 \mathrm{J}$

$S1:$ The efficiency of a heat engine can be $1,$ but the coefficient of performance of a refrigerator can never be infinity.
$S2:$ The first law of thermodynamics is basically the principle of conservation of energy.
$S3:$ The second law of thermodynamics does not allow several phenomena consistent with the first law.
$S4:$ A process,whose only result is to transfer heat from a colder to a hotter object, is impossible.

